Cargando…

A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams

[Image: see text] Phenol and its derivatives are highly toxic chemicals and are widely used in various industrial applications. Therefore, the industrial wastewater streams must be treated to lower the concentration of phenol before discharge. At the same time, food waste has been a major environmen...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Lei, Gamliel, David P., Markunas, Brianna, Valla, Julia A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028020/
https://www.ncbi.nlm.nih.gov/pubmed/33842758
http://dx.doi.org/10.1021/acsomega.0c06029
_version_ 1783675907517448192
author Yu, Lei
Gamliel, David P.
Markunas, Brianna
Valla, Julia A.
author_facet Yu, Lei
Gamliel, David P.
Markunas, Brianna
Valla, Julia A.
author_sort Yu, Lei
collection PubMed
description [Image: see text] Phenol and its derivatives are highly toxic chemicals and are widely used in various industrial applications. Therefore, the industrial wastewater streams must be treated to lower the concentration of phenol before discharge. At the same time, food waste has been a major environmental problem globally and the scientific community is eagerly seeking effective management solutions. The objective of this study was to understand the potential of utilizing food waste as a renewable and sustainable resource for the production of activated carbons for the removal of phenol from water streams. The food waste was pyrolyzed and physically activated by steam. The pyrolysis and activation conditions were optimized to obtain activated carbons with high surface area. The activated carbon with the highest surface area, 745 m(2) g(–1), was derived via activation at 950 °C for 1 h. A detailed characterization of the physicochemical and morphological properties of the activated carbons derived from food waste was performed and a comprehensive adsorption study was conducted to investigate the potential of using the activated carbons for phenol removal from water streams. The effects of pH, contact time, and initial concentration of phenol in water were studied and adsorption models were applied to experimental data to interpret the adsorption process. A remarkable phenol adsorption capacity of 568 mg g(–1) was achieved. The results indicated that the pseudo-second-order kinetic model was better over the pseudo-second-order kinetic model to describe the kinetics of adsorption. The intraparticle diffusion model showed multiple regions, suggesting that the intraparticle diffusion was not the sole rate-controlling step of adsorption. The Langmuir isotherm model was the best model out of Freundlich, Temkin, and Dubinin–Radushkevich models to describe the phenol adsorption on activated carbons derived from food waste. This study demonstrated that food waste could be utilized to produce activated carbon and it showed promising capacity on phenol removal.
format Online
Article
Text
id pubmed-8028020
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-80280202021-04-09 A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams Yu, Lei Gamliel, David P. Markunas, Brianna Valla, Julia A. ACS Omega [Image: see text] Phenol and its derivatives are highly toxic chemicals and are widely used in various industrial applications. Therefore, the industrial wastewater streams must be treated to lower the concentration of phenol before discharge. At the same time, food waste has been a major environmental problem globally and the scientific community is eagerly seeking effective management solutions. The objective of this study was to understand the potential of utilizing food waste as a renewable and sustainable resource for the production of activated carbons for the removal of phenol from water streams. The food waste was pyrolyzed and physically activated by steam. The pyrolysis and activation conditions were optimized to obtain activated carbons with high surface area. The activated carbon with the highest surface area, 745 m(2) g(–1), was derived via activation at 950 °C for 1 h. A detailed characterization of the physicochemical and morphological properties of the activated carbons derived from food waste was performed and a comprehensive adsorption study was conducted to investigate the potential of using the activated carbons for phenol removal from water streams. The effects of pH, contact time, and initial concentration of phenol in water were studied and adsorption models were applied to experimental data to interpret the adsorption process. A remarkable phenol adsorption capacity of 568 mg g(–1) was achieved. The results indicated that the pseudo-second-order kinetic model was better over the pseudo-second-order kinetic model to describe the kinetics of adsorption. The intraparticle diffusion model showed multiple regions, suggesting that the intraparticle diffusion was not the sole rate-controlling step of adsorption. The Langmuir isotherm model was the best model out of Freundlich, Temkin, and Dubinin–Radushkevich models to describe the phenol adsorption on activated carbons derived from food waste. This study demonstrated that food waste could be utilized to produce activated carbon and it showed promising capacity on phenol removal. American Chemical Society 2021-03-25 /pmc/articles/PMC8028020/ /pubmed/33842758 http://dx.doi.org/10.1021/acsomega.0c06029 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yu, Lei
Gamliel, David P.
Markunas, Brianna
Valla, Julia A.
A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title_full A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title_fullStr A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title_full_unstemmed A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title_short A Promising Solution for Food Waste: Preparing Activated Carbons for Phenol Removal from Water Streams
title_sort promising solution for food waste: preparing activated carbons for phenol removal from water streams
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028020/
https://www.ncbi.nlm.nih.gov/pubmed/33842758
http://dx.doi.org/10.1021/acsomega.0c06029
work_keys_str_mv AT yulei apromisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT gamlieldavidp apromisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT markunasbrianna apromisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT vallajuliaa apromisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT yulei promisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT gamlieldavidp promisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT markunasbrianna promisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams
AT vallajuliaa promisingsolutionforfoodwastepreparingactivatedcarbonsforphenolremovalfromwaterstreams