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Superalkali–Alkalide Interactions and Ion Pairing in Low-Polarity Solvents

[Image: see text] The nature of anionic alkali metals in solution is traditionally thought to be “gaslike” and unperturbed. In contrast to this noninteracting picture, we present experimental and computational data herein that support ion pairing in alkalide solutions. Concentration dependent ionic...

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Detalles Bibliográficos
Autores principales: Riedel, René, Seel, Andrew G., Malko, Daniel, Miller, Daniel P., Sperling, Brendan T., Choi, Heungjae, Headen, Thomas F., Zurek, Eva, Porch, Adrian, Kucernak, Anthony, Pyper, Nicholas C., Edwards, Peter P., Barrett, Anthony G. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028040/
https://www.ncbi.nlm.nih.gov/pubmed/33660507
http://dx.doi.org/10.1021/jacs.1c00115