Cargando…

Superalkali–Alkalide Interactions and Ion Pairing in Low-Polarity Solvents

[Image: see text] The nature of anionic alkali metals in solution is traditionally thought to be “gaslike” and unperturbed. In contrast to this noninteracting picture, we present experimental and computational data herein that support ion pairing in alkalide solutions. Concentration dependent ionic...

Descripción completa

Detalles Bibliográficos
Autores principales:	Riedel, René, Seel, Andrew G., Malko, Daniel, Miller, Daniel P., Sperling, Brendan T., Choi, Heungjae, Headen, Thomas F., Zurek, Eva, Porch, Adrian, Kucernak, Anthony, Pyper, Nicholas C., Edwards, Peter P., Barrett, Anthony G. M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8028040/ https://www.ncbi.nlm.nih.gov/pubmed/33660507 http://dx.doi.org/10.1021/jacs.1c00115

Ejemplares similares

Superalkali Coated Rydberg Molecules
por: Tkachenko, Nikolay V., et al.
Publicado: (2022)

In situ electrochemical quantification of active sites in Fe–N/C non-precious metal catalysts
por: Malko, Daniel, et al.
Publicado: (2016)

Editorial: Superhalogens & superalkalis: Exploration of structure, properties and applications
por: Srivastava, Ambrish Kumar, et al.
Publicado: (2022)

CO(2) Activation Within a Superalkali-Doped Fullerene
por: Meloni, Giovanni, et al.
Publicado: (2021)

A nonlinear optical switch induced by an external electric field: inorganic alkaline–earth alkalide
por: Li, Bo, et al.
Publicado: (2019)

Designing Special Nonmetallic Superalkalis Based on a Cage-like Adamanzane Complexant
por: Ye, Ya-Ling, et al.
Publicado: (2022)

Weak Interactions in Dimethyl Sulfoxide (DMSO)–Tertiary Amide Solutions: The Versatility of DMSO as a Solvent
por: Di Mino, Camilla, et al.
Publicado: (2023)

Recent advances in in silico design and characterization of superalkali-based materials and their potential applications: A review
por: Pandey, Sarvesh Kumar, et al.
Publicado: (2022)

Cervical Tissue Hydration Level Monitoring by a Resonant Microwave Coaxial Probe
por: Choi, Heungjae, et al.
Publicado: (2022)

Enhanced nonlinear optical response of alkalides based on stacked Janus all-cis-1,2,3,4,5,6-hexafluorocyclohexane
por: Sohaib, Muhammad, et al.
Publicado: (2023)

DFT study of superhalogen and superalkali doped graphitic carbon nitride and its non-linear optical properties
por: Khan, Asmat Ullah, et al.
Publicado: (2021)

Design and In Vitro Interference Test of Microwave Noninvasive Blood Glucose Monitoring Sensor
por: Choi, Heungjae, et al.
Publicado: (2015)

Remarkable static and dynamic NLO response of alkali and superalkali doped macrocyclic [hexa-]thiophene complexes; a DFT approach
por: Sajid, Hasnain, et al.
Publicado: (2021)

Experimental functional map of a polymer electrolyte fuel cell
por: Brett, Daniel JL, et al.
Publicado: (2008)

Bioluminescence of Vibrio fischeri: bacteria respond quickly and sensitively to pulsed microwave electric (but not magnetic) fields
por: Williams, Catrin F., et al.
Publicado: (2019)

Novel and Polynuclear K- and Na-Based Superalkali Hydroxides as Superbases Better Than Li-Related Species and Their Enhanced Properties: An Ab Initio Exploration
por: Pandey, Sarvesh Kumar
Publicado: (2021)

Intermediate Range Order in Metal–Ammonia Solutions: Pure and Na-Doped Ca-NH(3)
por: Nicholas, Thomas C., et al.
Publicado: (2021)

Real-Time In Situ Monitoring of CO(2) Electroreduction in the Liquid and Gas Phases by Coupled Mass Spectrometry and Localized Electrochemistry
por: Zhang, Guohui, et al.
Publicado: (2022)

OEEF-Driven Intramolecular Self-Redox of Superalkali Rb(3)BeB(6)Be′Rb′(3): A High-Performance Candidate for NLO Molecular Switch
por: Zeng, Jia-Mei, et al.
Publicado: (2023)

Strong structuring arising from weak cooperative O-H···π and C-H···O hydrogen bonding in benzene-methanol solution
por: Di Mino, Camilla, et al.
Publicado: (2023)

Oxygen Reduction Reaction Activity in Non-Precious Single-Atom (M–N/C) Catalysts—Contribution of Metal and Carbon/Nitrogen Framework-Based Sites
por: Gong, Mengjun, et al.
Publicado: (2023)

Self-assembling two-dimensional nanophotonic arrays for reflectivity-based sensing
por: Ma, Ye, et al.
Publicado: (2020)

The local ordering of polar solvents around crystalline carbon nitride nanosheets in solution
por: Wilding, Martin C., et al.
Publicado: (2023)

Case of Incidental Asymptomatic Carotid Body Paraganglioma in a Patient with Infectious Mononucleosis
por: Cox, Eric L, et al.
Publicado: (2019)

Minority Populations and Health: An Introduction to Health Disparities in the United States
por: Headen, Sandra
Publicado: (2005)

The impact of different types of parental support behaviours on child physical activity, healthy eating, and screen time: a cross-sectional study
por: Pyper, Evelyn, et al.
Publicado: (2016)

Do parents’ support behaviours predict whether or not their children get sufficient sleep? A cross-sectional study
por: Pyper, Evelyn, et al.
Publicado: (2017)

Quark pair condensation and confinement
por: Hey, Anthony J G, et al.
Publicado: (1978)

Electron Solvation and the Unique Liquid Structure of a Mixed‐Amine Expanded Metal: The Saturated Li–NH(3)–MeNH(2) System
por: Seel, Andrew G., et al.
Publicado: (2017)

Rapid, non-invasive characterization of the dispersity of emulsions via microwaves
por: Yan, Yuqiang, et al.
Publicado: (2018)

The treatment of femoral shaft fractures using a cast brace.
por: Pyper, P. C., et al.
Publicado: (1981)

Self-Calibrating Magnetometer-Free Inertial Motion Tracking of 2-DoF Joints
por: Laidig, Daniel, et al.
Publicado: (2022)

Microwave characterisation of carbon nanotube powders
por: Porch, Adrian, et al.
Publicado: (2012)

The Solvent-Dependent Photophysics of Diphenyloctatetraene
por: Polak, Daniel W., et al.
Publicado: (2023)

Structural and solvent control over activation parameters for a pair of retro Diels-Alder reactions
por: Widstrom, Andrea L., et al.
Publicado: (2019)

Water in Protic Ionic Liquid Electrolytes: From Solvent Separated Ion Pairs to Water Clusters
por: Gehrke, Sascha, et al.
Publicado: (2021)

Porphyrin-Embedded Silicate Materials for Detection of Hydrocarbon Solvents
por: Johnson, Brandy J., et al.
Publicado: (2011)

Amplification, Decoherence, and the Acquisition of Information by Spin Environments
por: Zwolak, Michael, et al.
Publicado: (2016)

A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate
por: D'Souza, Malcolm J., et al.
Publicado: (2011)

Spectroscopic Investigation of DCCH and FTSC as a potential pair for Förster Resonance Energy Transfer in different solvents
por: Urstöger, Georg, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_u21mdt6q1rnmlp8njrancg7sbe