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Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
[Image: see text] Herein, we present the first example of the activation of small molecules by P–B–P bond systems. The reactivity study involves reactions of two selected diphosphinoboranes, (t-Bu(2)P)(2)BPh (1′) and (Cy(2)P)(2)BNiPr(2) (2), that differ in terms of their structural and electronic pr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8041279/ https://www.ncbi.nlm.nih.gov/pubmed/33657801 http://dx.doi.org/10.1021/acs.inorgchem.0c03563 |