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Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe

A green, scalable, and sustainable approach to prepare aqueous fullerene dispersions (AFD) C(60), C(70), endohedral metallofullerene Gd@C(82), and their derivatives C(60)Cl(6), C(70)Cl(10), and supramolecular and ester-like derivatives, 10 fullerene species total, is proposed. For the first time, an...

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Autores principales: Mikheev, Ivan V., Pirogova, Mariya O., Usoltseva, Liliia O., Uzhel, Anna S., Bolotnik, Timofey A., Kareev, Ivan E., Bubnov, Viacheslav P., Lukonina, Natalia S., Volkov, Dmitry S., Goryunkov, Alexey A., Korobov, Mikhail V., Proskurnin, Mikhail A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8044700/
https://www.ncbi.nlm.nih.gov/pubmed/33799110
http://dx.doi.org/10.1016/j.ultsonch.2021.105533
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author Mikheev, Ivan V.
Pirogova, Mariya O.
Usoltseva, Liliia O.
Uzhel, Anna S.
Bolotnik, Timofey A.
Kareev, Ivan E.
Bubnov, Viacheslav P.
Lukonina, Natalia S.
Volkov, Dmitry S.
Goryunkov, Alexey A.
Korobov, Mikhail V.
Proskurnin, Mikhail A.
author_facet Mikheev, Ivan V.
Pirogova, Mariya O.
Usoltseva, Liliia O.
Uzhel, Anna S.
Bolotnik, Timofey A.
Kareev, Ivan E.
Bubnov, Viacheslav P.
Lukonina, Natalia S.
Volkov, Dmitry S.
Goryunkov, Alexey A.
Korobov, Mikhail V.
Proskurnin, Mikhail A.
author_sort Mikheev, Ivan V.
collection PubMed
description A green, scalable, and sustainable approach to prepare aqueous fullerene dispersions (AFD) C(60), C(70), endohedral metallofullerene Gd@C(82), and their derivatives C(60)Cl(6), C(70)Cl(10), and supramolecular and ester-like derivatives, 10 fullerene species total, is proposed. For the first time, an immersed ultrasonic probe was used to preparing dispersions for pristine fullerenes without addends. Both ultrasound-assisted solvent-exchange and direct sonication techniques for AFD preparation using an immersed probe were tested. The average time for AFD preparation decreases 10–15 times compared to an ultrasound-bath-assisted technique, while final fullerene concentrations in AFDs remained at tens of ppm (up to 80 ppm). The aqueous dispersions showed long-term stability, a negatively charged surface with a zeta potential up to –32 mV with an average nanocluster diameter of no more than 180 nm. The total anionic and cationic compositions of samples were found by inductively coupled plasma atomic emission spectroscopy and chromatographic techniques. The highlights and challenges of using an ultrasound probe for AFD production are discussed.
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spelling pubmed-80447002021-04-16 Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe Mikheev, Ivan V. Pirogova, Mariya O. Usoltseva, Liliia O. Uzhel, Anna S. Bolotnik, Timofey A. Kareev, Ivan E. Bubnov, Viacheslav P. Lukonina, Natalia S. Volkov, Dmitry S. Goryunkov, Alexey A. Korobov, Mikhail V. Proskurnin, Mikhail A. Ultrason Sonochem Original Research Article A green, scalable, and sustainable approach to prepare aqueous fullerene dispersions (AFD) C(60), C(70), endohedral metallofullerene Gd@C(82), and their derivatives C(60)Cl(6), C(70)Cl(10), and supramolecular and ester-like derivatives, 10 fullerene species total, is proposed. For the first time, an immersed ultrasonic probe was used to preparing dispersions for pristine fullerenes without addends. Both ultrasound-assisted solvent-exchange and direct sonication techniques for AFD preparation using an immersed probe were tested. The average time for AFD preparation decreases 10–15 times compared to an ultrasound-bath-assisted technique, while final fullerene concentrations in AFDs remained at tens of ppm (up to 80 ppm). The aqueous dispersions showed long-term stability, a negatively charged surface with a zeta potential up to –32 mV with an average nanocluster diameter of no more than 180 nm. The total anionic and cationic compositions of samples were found by inductively coupled plasma atomic emission spectroscopy and chromatographic techniques. The highlights and challenges of using an ultrasound probe for AFD production are discussed. Elsevier 2021-03-19 /pmc/articles/PMC8044700/ /pubmed/33799110 http://dx.doi.org/10.1016/j.ultsonch.2021.105533 Text en © 2021 The Authors https://creativecommons.org/licenses/by/4.0/This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Original Research Article
Mikheev, Ivan V.
Pirogova, Mariya O.
Usoltseva, Liliia O.
Uzhel, Anna S.
Bolotnik, Timofey A.
Kareev, Ivan E.
Bubnov, Viacheslav P.
Lukonina, Natalia S.
Volkov, Dmitry S.
Goryunkov, Alexey A.
Korobov, Mikhail V.
Proskurnin, Mikhail A.
Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title_full Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title_fullStr Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title_full_unstemmed Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title_short Green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: The pros and cons of an ultrasonic probe
title_sort green and rapid preparation of long-term stable aqueous dispersions of fullerenes and endohedral fullerenes: the pros and cons of an ultrasonic probe
topic Original Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8044700/
https://www.ncbi.nlm.nih.gov/pubmed/33799110
http://dx.doi.org/10.1016/j.ultsonch.2021.105533
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