Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings

[Image: see text] In stark contrast to phenothiazines and their prevalence for cross-dehydrogenative amination reactions, benzophenothiazine has a pronounced preference for cross-dehydrogenative C–C bond-forming reactions. Moreover, the substrate is very versatile, leading to several new classes of...

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Autores principales: Bub, Christina L., Thönnißen, Vinzenz, Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8046291/
https://www.ncbi.nlm.nih.gov/pubmed/33196197
http://dx.doi.org/10.1021/acs.orglett.0c03354
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author Bub, Christina L.
Thönnißen, Vinzenz
Patureau, Frederic W.
author_facet Bub, Christina L.
Thönnißen, Vinzenz
Patureau, Frederic W.
author_sort Bub, Christina L.
collection PubMed
description [Image: see text] In stark contrast to phenothiazines and their prevalence for cross-dehydrogenative amination reactions, benzophenothiazine has a pronounced preference for cross-dehydrogenative C–C bond-forming reactions. Moreover, the substrate is very versatile, leading to several new classes of C–C bond-forming reactions and many new oxidative coupling product architectures, including unprecedented indole fused paddlewheel-like structures.
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spelling pubmed-80462912021-04-15 Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings Bub, Christina L. Thönnißen, Vinzenz Patureau, Frederic W. Org Lett [Image: see text] In stark contrast to phenothiazines and their prevalence for cross-dehydrogenative amination reactions, benzophenothiazine has a pronounced preference for cross-dehydrogenative C–C bond-forming reactions. Moreover, the substrate is very versatile, leading to several new classes of C–C bond-forming reactions and many new oxidative coupling product architectures, including unprecedented indole fused paddlewheel-like structures. American Chemical Society 2020-11-16 2020-12-04 /pmc/articles/PMC8046291/ /pubmed/33196197 http://dx.doi.org/10.1021/acs.orglett.0c03354 Text en © 2020 American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Bub, Christina L.
Thönnißen, Vinzenz
Patureau, Frederic W.
Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title_full Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title_fullStr Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title_full_unstemmed Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title_short Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings
title_sort benzophenothiazine and its cr(iii)-catalyzed cross dehydrogenative couplings
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8046291/
https://www.ncbi.nlm.nih.gov/pubmed/33196197
http://dx.doi.org/10.1021/acs.orglett.0c03354
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