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Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
[Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (R...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047673/ https://www.ncbi.nlm.nih.gov/pubmed/33869939 http://dx.doi.org/10.1021/acsomega.1c00143 |
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author | Kumar, Gyanendra Masram, Dhanraj T. |
author_facet | Kumar, Gyanendra Masram, Dhanraj T. |
author_sort | Kumar, Gyanendra |
collection | PubMed |
description | [Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (RhB) dye. The removal efficiency of RhB is found to be 60.64% (151.62 mg·g(–1)) at 500 ppm. About 98.88% of RhB is removed within 5 min of contact time and increased up to 99.68% up to 10 min. The removal rate of MOF-5@GO nanocomposites is much better than that of pristine MOF-5. Equilibrium adsorption capacity is determined by a series of different experimental conditions such as pH, time, and concentration of dye solution. Although the results also showed that dye removal on MOF-5@GO nanocomposites is well described by the Langmuir isotherm (R(2) = 0.9703), the adsorption kinetics data reveals pseudo-second-order (R(2) = 0.9908). The synthesized nanocomposite is efficient for removal of dye, cost-effective, and reusable. Additionally, stability and self-degradation studies of pure RhB are reported in aqueous solution for up to 120 days at different pH values (pH 1–12). |
format | Online Article Text |
id | pubmed-8047673 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-80476732021-04-16 Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water Kumar, Gyanendra Masram, Dhanraj T. ACS Omega [Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (RhB) dye. The removal efficiency of RhB is found to be 60.64% (151.62 mg·g(–1)) at 500 ppm. About 98.88% of RhB is removed within 5 min of contact time and increased up to 99.68% up to 10 min. The removal rate of MOF-5@GO nanocomposites is much better than that of pristine MOF-5. Equilibrium adsorption capacity is determined by a series of different experimental conditions such as pH, time, and concentration of dye solution. Although the results also showed that dye removal on MOF-5@GO nanocomposites is well described by the Langmuir isotherm (R(2) = 0.9703), the adsorption kinetics data reveals pseudo-second-order (R(2) = 0.9908). The synthesized nanocomposite is efficient for removal of dye, cost-effective, and reusable. Additionally, stability and self-degradation studies of pure RhB are reported in aqueous solution for up to 120 days at different pH values (pH 1–12). American Chemical Society 2021-03-30 /pmc/articles/PMC8047673/ /pubmed/33869939 http://dx.doi.org/10.1021/acsomega.1c00143 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Kumar, Gyanendra Masram, Dhanraj T. Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water |
title | Sustainable Synthesis of MOF-5@GO Nanocomposites for
Efficient Removal of Rhodamine B from Water |
title_full | Sustainable Synthesis of MOF-5@GO Nanocomposites for
Efficient Removal of Rhodamine B from Water |
title_fullStr | Sustainable Synthesis of MOF-5@GO Nanocomposites for
Efficient Removal of Rhodamine B from Water |
title_full_unstemmed | Sustainable Synthesis of MOF-5@GO Nanocomposites for
Efficient Removal of Rhodamine B from Water |
title_short | Sustainable Synthesis of MOF-5@GO Nanocomposites for
Efficient Removal of Rhodamine B from Water |
title_sort | sustainable synthesis of mof-5@go nanocomposites for
efficient removal of rhodamine b from water |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047673/ https://www.ncbi.nlm.nih.gov/pubmed/33869939 http://dx.doi.org/10.1021/acsomega.1c00143 |
work_keys_str_mv | AT kumargyanendra sustainablesynthesisofmof5gonanocompositesforefficientremovalofrhodaminebfromwater AT masramdhanrajt sustainablesynthesisofmof5gonanocompositesforefficientremovalofrhodaminebfromwater |