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Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water

[Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (R...

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Autores principales: Kumar, Gyanendra, Masram, Dhanraj T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047673/
https://www.ncbi.nlm.nih.gov/pubmed/33869939
http://dx.doi.org/10.1021/acsomega.1c00143
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author Kumar, Gyanendra
Masram, Dhanraj T.
author_facet Kumar, Gyanendra
Masram, Dhanraj T.
author_sort Kumar, Gyanendra
collection PubMed
description [Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (RhB) dye. The removal efficiency of RhB is found to be 60.64% (151.62 mg·g(–1)) at 500 ppm. About 98.88% of RhB is removed within 5 min of contact time and increased up to 99.68% up to 10 min. The removal rate of MOF-5@GO nanocomposites is much better than that of pristine MOF-5. Equilibrium adsorption capacity is determined by a series of different experimental conditions such as pH, time, and concentration of dye solution. Although the results also showed that dye removal on MOF-5@GO nanocomposites is well described by the Langmuir isotherm (R(2) = 0.9703), the adsorption kinetics data reveals pseudo-second-order (R(2) = 0.9908). The synthesized nanocomposite is efficient for removal of dye, cost-effective, and reusable. Additionally, stability and self-degradation studies of pure RhB are reported in aqueous solution for up to 120 days at different pH values (pH 1–12).
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spelling pubmed-80476732021-04-16 Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water Kumar, Gyanendra Masram, Dhanraj T. ACS Omega [Image: see text] Herein, a metal–organic framework (MOF-5) is synthesized by a solvothermal process and graphene oxide (GO) is prepared from the improved Hummer’s method. The synthesis of MOF-5@GO nanocomposites is one-pot process via a grinding method and employed for the removal of Rhodamine B (RhB) dye. The removal efficiency of RhB is found to be 60.64% (151.62 mg·g(–1)) at 500 ppm. About 98.88% of RhB is removed within 5 min of contact time and increased up to 99.68% up to 10 min. The removal rate of MOF-5@GO nanocomposites is much better than that of pristine MOF-5. Equilibrium adsorption capacity is determined by a series of different experimental conditions such as pH, time, and concentration of dye solution. Although the results also showed that dye removal on MOF-5@GO nanocomposites is well described by the Langmuir isotherm (R(2) = 0.9703), the adsorption kinetics data reveals pseudo-second-order (R(2) = 0.9908). The synthesized nanocomposite is efficient for removal of dye, cost-effective, and reusable. Additionally, stability and self-degradation studies of pure RhB are reported in aqueous solution for up to 120 days at different pH values (pH 1–12). American Chemical Society 2021-03-30 /pmc/articles/PMC8047673/ /pubmed/33869939 http://dx.doi.org/10.1021/acsomega.1c00143 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Kumar, Gyanendra
Masram, Dhanraj T.
Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title_full Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title_fullStr Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title_full_unstemmed Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title_short Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water
title_sort sustainable synthesis of mof-5@go nanocomposites for efficient removal of rhodamine b from water
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047673/
https://www.ncbi.nlm.nih.gov/pubmed/33869939
http://dx.doi.org/10.1021/acsomega.1c00143
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