Cargando…

Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data

[Image: see text] A simple corresponding state-based correlation, whose analytical expression contains just one term with an exponential function, is proposed to calculate the surface tension of 36 silanes, 29 carboxylic acids, and 81 refrigerants as a function of temperature. This correlation only...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Shangguo, Tian, Jianxiang, Jiang, Hua, Mulero, Ángel, Cachadiña, Isidro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047697/
https://www.ncbi.nlm.nih.gov/pubmed/33869974
http://dx.doi.org/10.1021/acsomega.1c00913
_version_ 1783679092228358144
author Yang, Shangguo
Tian, Jianxiang
Jiang, Hua
Mulero, Ángel
Cachadiña, Isidro
author_facet Yang, Shangguo
Tian, Jianxiang
Jiang, Hua
Mulero, Ángel
Cachadiña, Isidro
author_sort Yang, Shangguo
collection PubMed
description [Image: see text] A simple corresponding state-based correlation, whose analytical expression contains just one term with an exponential function, is proposed to calculate the surface tension of 36 silanes, 29 carboxylic acids, and 81 refrigerants as a function of temperature. This correlation only requires critical temperature, maximum value of surface tension, and its corresponding temperature in the DIPPR database as inputs for each liquid considered. The correlation allows us to calculate the accepted DIPPR data for silanes with a mean absolute average deviation (AAD) of 2.75%, 2.42% for acids, and 3.32% for refrigerants. Moreover, it gives AADs below 3% for 99 fluids. The mean deviation for the 146 fluids is 3.0%, which is practically equal to the results obtained when two terms are used in the analytical expression.
format Online
Article
Text
id pubmed-8047697
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-80476972021-04-16 Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data Yang, Shangguo Tian, Jianxiang Jiang, Hua Mulero, Ángel Cachadiña, Isidro ACS Omega [Image: see text] A simple corresponding state-based correlation, whose analytical expression contains just one term with an exponential function, is proposed to calculate the surface tension of 36 silanes, 29 carboxylic acids, and 81 refrigerants as a function of temperature. This correlation only requires critical temperature, maximum value of surface tension, and its corresponding temperature in the DIPPR database as inputs for each liquid considered. The correlation allows us to calculate the accepted DIPPR data for silanes with a mean absolute average deviation (AAD) of 2.75%, 2.42% for acids, and 3.32% for refrigerants. Moreover, it gives AADs below 3% for 99 fluids. The mean deviation for the 146 fluids is 3.0%, which is practically equal to the results obtained when two terms are used in the analytical expression. American Chemical Society 2021-03-31 /pmc/articles/PMC8047697/ /pubmed/33869974 http://dx.doi.org/10.1021/acsomega.1c00913 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yang, Shangguo
Tian, Jianxiang
Jiang, Hua
Mulero, Ángel
Cachadiña, Isidro
Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title_full Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title_fullStr Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title_full_unstemmed Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title_short Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data
title_sort surface tension for silanes, refrigerants, and carboxylic acids: simple corresponding state correlations versus dippr data
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8047697/
https://www.ncbi.nlm.nih.gov/pubmed/33869974
http://dx.doi.org/10.1021/acsomega.1c00913
work_keys_str_mv AT yangshangguo surfacetensionforsilanesrefrigerantsandcarboxylicacidssimplecorrespondingstatecorrelationsversusdipprdata
AT tianjianxiang surfacetensionforsilanesrefrigerantsandcarboxylicacidssimplecorrespondingstatecorrelationsversusdipprdata
AT jianghua surfacetensionforsilanesrefrigerantsandcarboxylicacidssimplecorrespondingstatecorrelationsversusdipprdata
AT muleroangel surfacetensionforsilanesrefrigerantsandcarboxylicacidssimplecorrespondingstatecorrelationsversusdipprdata
AT cachadinaisidro surfacetensionforsilanesrefrigerantsandcarboxylicacidssimplecorrespondingstatecorrelationsversusdipprdata