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Minimization of Back‐Electron Transfer Enables the Elusive sp(3) C−H Functionalization of Secondary Anilines
Anilines are some of the most used class of substrates for application in photoinduced electron transfer. N,N‐Dialkyl‐derivatives enable radical generation α to the N‐atom by oxidation followed by deprotonation. This approach is however elusive to monosubstituted anilines owing to fast back‐electron...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048505/ https://www.ncbi.nlm.nih.gov/pubmed/33459469 http://dx.doi.org/10.1002/anie.202100051 |