A Solid‐State Intramolecular Wittig Reaction Enables Efficient Synthesis of Endofullerenes Including Ne@C(60), (3)He@C(60), and HD@C(60)

An open‐cage fullerene incorporating phosphorous ylid and carbonyl group moieties on the rim of the orifice can be filled with gases (H(2), He, Ne) in the solid state, and the cage opening then contracted in situ by raising the temperature to complete an intramolecular Wittig reaction, trapping the...

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Detalles Bibliográficos
Autores principales: Hoffman, Gabriela, Walkey, Mark C., Gräsvik, John, Bacanu, George R., Alom, Shamim, Bloodworth, Sally, Light, Mark E., Levitt, Malcolm H., Whitby, Richard J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048630/
https://www.ncbi.nlm.nih.gov/pubmed/33554419
http://dx.doi.org/10.1002/anie.202100817

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