Enantioselective Nickel‐Catalyzed anti‐Arylmetallative Cyclizations onto Acyclic Ketones

Domino reactions involving nickel‐catalyzed additions of (hetero)arylboronic acids to alkynes, followed by cyclization of the alkenylnickel intermediates onto tethered acyclic ketones to give chiral tertiary‐alcohol‐containing products in high enantioselectivities, are described. The reversible E/Z...

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Detalles Bibliográficos
Autores principales: Green, Harley, Argent, Stephen P., Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048927/
https://www.ncbi.nlm.nih.gov/pubmed/33533065
http://dx.doi.org/10.1002/chem.202100143

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8048927/
https://www.ncbi.nlm.nih.gov/pubmed/33533065
http://dx.doi.org/10.1002/chem.202100143

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