Iron Oxidation in Escherichia coli Bacterioferritin Ferroxidase Centre, a Site Designed to React Rapidly with H(2)O(2) but Slowly with O(2)

Both O(2) and H(2)O(2) can oxidize iron at the ferroxidase center (FC) of Escherichia coli bacterioferritin (EcBfr) but mechanistic details of the two reactions need clarification. UV/Vis, EPR, and Mössbauer spectroscopies have been used to follow the reactions when apo‐EcBfr, pre‐loaded anaerobical...

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Detalles Bibliográficos
Autores principales: Pullin, Jacob, Wilson, Michael T., Clémancey, Martin, Blondin, Geneviève, Bradley, Justin M., Moore, Geoffrey R., Le Brun, Nick E., Lučić, Marina, Worrall, Jonathan A. R., Svistunenko, Dimitri A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8049013/
https://www.ncbi.nlm.nih.gov/pubmed/33482043
http://dx.doi.org/10.1002/anie.202015964

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