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Olefin oligomerization by main group Ga(3+) and Zn(2+) single site catalysts on SiO(2)

In heterogeneous catalysis, olefin oligomerization is typically performed on immobilized transition metal ions, such as Ni(2+) and Cr(3+). Here we report that silica-supported, single site catalysts containing immobilized, main group Zn(2+) and Ga(3+) ion sites catalyze ethylene and propylene oligom...

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Detalles Bibliográficos
Autores principales: LiBretto, Nicole J., Xu, Yinan, Quigley, Aubrey, Edwards, Ethan, Nargund, Rhea, Vega-Vila, Juan Carlos, Caulkins, Richard, Saxena, Arunima, Gounder, Rajamani, Greeley, Jeffrey, Zhang, Guanghui, Miller, Jeffrey T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8055657/
https://www.ncbi.nlm.nih.gov/pubmed/33875664
http://dx.doi.org/10.1038/s41467-021-22512-6