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Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy

A side-product present in the herbicide pyroxasulfone was synthesized. The construction of a bis(aryloxy)fluoromethane moiety was necessary, for which no existing method was available. We report a simple, new procedure which we applied to the synthesis of some of these unusual structures.

Detalles Bibliográficos
Autores principales: Recsei, Carl, Barda, Yaniv
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8056069/
https://www.ncbi.nlm.nih.gov/pubmed/33936312
http://dx.doi.org/10.3762/bjoc.17.70
Descripción
Sumario:A side-product present in the herbicide pyroxasulfone was synthesized. The construction of a bis(aryloxy)fluoromethane moiety was necessary, for which no existing method was available. We report a simple, new procedure which we applied to the synthesis of some of these unusual structures.