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Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy
A side-product present in the herbicide pyroxasulfone was synthesized. The construction of a bis(aryloxy)fluoromethane moiety was necessary, for which no existing method was available. We report a simple, new procedure which we applied to the synthesis of some of these unusual structures.
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8056069/ https://www.ncbi.nlm.nih.gov/pubmed/33936312 http://dx.doi.org/10.3762/bjoc.17.70 |
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| author | Recsei, Carl Barda, Yaniv |
| author_facet | Recsei, Carl Barda, Yaniv |
| author_sort | Recsei, Carl |
| collection | PubMed |
| description | A side-product present in the herbicide pyroxasulfone was synthesized. The construction of a bis(aryloxy)fluoromethane moiety was necessary, for which no existing method was available. We report a simple, new procedure which we applied to the synthesis of some of these unusual structures. |
| format | Online Article Text |
| id | pubmed-8056069 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-80560692021-04-30 Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy Recsei, Carl Barda, Yaniv Beilstein J Org Chem Letter A side-product present in the herbicide pyroxasulfone was synthesized. The construction of a bis(aryloxy)fluoromethane moiety was necessary, for which no existing method was available. We report a simple, new procedure which we applied to the synthesis of some of these unusual structures. Beilstein-Institut 2021-04-12 /pmc/articles/PMC8056069/ /pubmed/33936312 http://dx.doi.org/10.3762/bjoc.17.70 Text en Copyright © 2021, Recsei and Barda https://creativecommons.org/licenses/by/4.0/https://www.beilstein-journals.org/bjoc/terms/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). Please note that the reuse, redistribution and reproduction in particular requires that the author(s) and source are credited and that individual graphics may be subject to special legal provisions. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms/terms) |
| spellingShingle | Letter Recsei, Carl Barda, Yaniv Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title | Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title_full | Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title_fullStr | Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title_full_unstemmed | Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title_short | Synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| title_sort | synthesis of bis(aryloxy)fluoromethanes using a heterodihalocarbene strategy |
| topic | Letter |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8056069/ https://www.ncbi.nlm.nih.gov/pubmed/33936312 http://dx.doi.org/10.3762/bjoc.17.70 |
| work_keys_str_mv | AT recseicarl synthesisofbisaryloxyfluoromethanesusingaheterodihalocarbenestrategy AT bardayaniv synthesisofbisaryloxyfluoromethanesusingaheterodihalocarbenestrategy |