Enzymatic Synthesis of 1,5-Anhydro-4-O-β-D-glucopyranosyl-D-fructose Using Cellobiose Phosphorylase and Its Spontaneous Decomposition via β-Elimination

Cellobiose phosphorylase from Cellvibrio gilvus was used to prepare 1,5-anhydro-4-O-β-D-glucopyranosyl-D-fructose [βGlc(1→4)AF] from 1,5-anhydro-D-fructose and α-D-glucose 1-phosphate. βGlc(1→4)AF decomposed into D-glucose and ascopyrone T via β-elimination. Higher pH and temperature caused faster d...

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Detalles Bibliográficos
Autores principales: Kajiki, Takahito, Yoshinaga, Kazuhiro, Komba, Shiro, Kitaoka, Motomitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Japanese Society of Applied Glycoscience 2017
Materias:
Regular Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8056936/
https://www.ncbi.nlm.nih.gov/pubmed/34354501
http://dx.doi.org/10.5458/jag.jag.JAG-2017_010

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8056936/
https://www.ncbi.nlm.nih.gov/pubmed/34354501
http://dx.doi.org/10.5458/jag.jag.JAG-2017_010

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