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A high-conductivity n-type polymeric ink for printed electronics

Conducting polymers, such as the p-doped poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), have enabled the development of an array of opto- and bio-electronics devices. However, to make these technologies truly pervasive, stable and easily processable, n-doped conducting polymer...

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Autores principales: Yang, Chi-Yuan, Stoeckel, Marc-Antoine, Ruoko, Tero-Petri, Wu, Han-Yan, Liu, Xianjie, Kolhe, Nagesh B., Wu, Ziang, Puttisong, Yuttapoom, Musumeci, Chiara, Massetti, Matteo, Sun, Hengda, Xu, Kai, Tu, Deyu, Chen, Weimin M., Woo, Han Young, Fahlman, Mats, Jenekhe, Samson A., Berggren, Magnus, Fabiano, Simone
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8060302/
https://www.ncbi.nlm.nih.gov/pubmed/33883549
http://dx.doi.org/10.1038/s41467-021-22528-y
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author Yang, Chi-Yuan
Stoeckel, Marc-Antoine
Ruoko, Tero-Petri
Wu, Han-Yan
Liu, Xianjie
Kolhe, Nagesh B.
Wu, Ziang
Puttisong, Yuttapoom
Musumeci, Chiara
Massetti, Matteo
Sun, Hengda
Xu, Kai
Tu, Deyu
Chen, Weimin M.
Woo, Han Young
Fahlman, Mats
Jenekhe, Samson A.
Berggren, Magnus
Fabiano, Simone
author_facet Yang, Chi-Yuan
Stoeckel, Marc-Antoine
Ruoko, Tero-Petri
Wu, Han-Yan
Liu, Xianjie
Kolhe, Nagesh B.
Wu, Ziang
Puttisong, Yuttapoom
Musumeci, Chiara
Massetti, Matteo
Sun, Hengda
Xu, Kai
Tu, Deyu
Chen, Weimin M.
Woo, Han Young
Fahlman, Mats
Jenekhe, Samson A.
Berggren, Magnus
Fabiano, Simone
author_sort Yang, Chi-Yuan
collection PubMed
description Conducting polymers, such as the p-doped poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), have enabled the development of an array of opto- and bio-electronics devices. However, to make these technologies truly pervasive, stable and easily processable, n-doped conducting polymers are also needed. Despite major efforts, no n-type equivalents to the benchmark PEDOT:PSS exist to date. Here, we report on the development of poly(benzimidazobenzophenanthroline):poly(ethyleneimine) (BBL:PEI) as an ethanol-based n-type conductive ink. BBL:PEI thin films yield an n-type electrical conductivity reaching 8 S cm(−1), along with excellent thermal, ambient, and solvent stability. This printable n-type mixed ion-electron conductor has several technological implications for realizing high-performance organic electronic devices, as demonstrated for organic thermoelectric generators with record high power output and n-type organic electrochemical transistors with a unique depletion mode of operation. BBL:PEI inks hold promise for the development of next-generation bioelectronics and wearable devices, in particular targeting novel functionality, efficiency, and power performance.
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spelling pubmed-80603022021-05-11 A high-conductivity n-type polymeric ink for printed electronics Yang, Chi-Yuan Stoeckel, Marc-Antoine Ruoko, Tero-Petri Wu, Han-Yan Liu, Xianjie Kolhe, Nagesh B. Wu, Ziang Puttisong, Yuttapoom Musumeci, Chiara Massetti, Matteo Sun, Hengda Xu, Kai Tu, Deyu Chen, Weimin M. Woo, Han Young Fahlman, Mats Jenekhe, Samson A. Berggren, Magnus Fabiano, Simone Nat Commun Article Conducting polymers, such as the p-doped poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), have enabled the development of an array of opto- and bio-electronics devices. However, to make these technologies truly pervasive, stable and easily processable, n-doped conducting polymers are also needed. Despite major efforts, no n-type equivalents to the benchmark PEDOT:PSS exist to date. Here, we report on the development of poly(benzimidazobenzophenanthroline):poly(ethyleneimine) (BBL:PEI) as an ethanol-based n-type conductive ink. BBL:PEI thin films yield an n-type electrical conductivity reaching 8 S cm(−1), along with excellent thermal, ambient, and solvent stability. This printable n-type mixed ion-electron conductor has several technological implications for realizing high-performance organic electronic devices, as demonstrated for organic thermoelectric generators with record high power output and n-type organic electrochemical transistors with a unique depletion mode of operation. BBL:PEI inks hold promise for the development of next-generation bioelectronics and wearable devices, in particular targeting novel functionality, efficiency, and power performance. Nature Publishing Group UK 2021-04-21 /pmc/articles/PMC8060302/ /pubmed/33883549 http://dx.doi.org/10.1038/s41467-021-22528-y Text en © The Author(s) 2021, corrected publication 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Yang, Chi-Yuan
Stoeckel, Marc-Antoine
Ruoko, Tero-Petri
Wu, Han-Yan
Liu, Xianjie
Kolhe, Nagesh B.
Wu, Ziang
Puttisong, Yuttapoom
Musumeci, Chiara
Massetti, Matteo
Sun, Hengda
Xu, Kai
Tu, Deyu
Chen, Weimin M.
Woo, Han Young
Fahlman, Mats
Jenekhe, Samson A.
Berggren, Magnus
Fabiano, Simone
A high-conductivity n-type polymeric ink for printed electronics
title A high-conductivity n-type polymeric ink for printed electronics
title_full A high-conductivity n-type polymeric ink for printed electronics
title_fullStr A high-conductivity n-type polymeric ink for printed electronics
title_full_unstemmed A high-conductivity n-type polymeric ink for printed electronics
title_short A high-conductivity n-type polymeric ink for printed electronics
title_sort high-conductivity n-type polymeric ink for printed electronics
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8060302/
https://www.ncbi.nlm.nih.gov/pubmed/33883549
http://dx.doi.org/10.1038/s41467-021-22528-y
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