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A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)]
The product obtained from the reaction of pyridine-2,3-dicarboxylic acid and hydrated copper(II) chloride in hot aqueous NaOH solution was determined by low temperature X-ray diffraction to be [Cu(3)(C(6)H(4)NO(3))(4)(OH)(2)(H(2)O)(2)](n) or [Cu(3)(μ-OH)(2)(μ-nicNO)(4)(H(2)O)(2)](n) (nicNO is pyr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8061101/ https://www.ncbi.nlm.nih.gov/pubmed/33953957 http://dx.doi.org/10.1107/S2056989021002000 |
| _version_ | 1783681497817939968 |
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| author | Mirzaei, Masoud Bazargan, Maryam Ebtehaj, Pouria Mague, Joel T. |
| author_facet | Mirzaei, Masoud Bazargan, Maryam Ebtehaj, Pouria Mague, Joel T. |
| author_sort | Mirzaei, Masoud |
| collection | PubMed |
| description | The product obtained from the reaction of pyridine-2,3-dicarboxylic acid and hydrated copper(II) chloride in hot aqueous NaOH solution was determined by low temperature X-ray diffraction to be [Cu(3)(C(6)H(4)NO(3))(4)(OH)(2)(H(2)O)(2)](n) or [Cu(3)(μ-OH)(2)(μ-nicNO)(4)(H(2)O)(2)](n) (nicNO is pyridine-3-carboxylate N-oxide), a structure obtained from room temperature data and reported previously. The present determination is improved in quality and treatment of the H atoms. A Hirshfeld surface analysis of the intermolecular interactions is presented. |
| format | Online Article Text |
| id | pubmed-8061101 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-80611012021-05-04 A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] Mirzaei, Masoud Bazargan, Maryam Ebtehaj, Pouria Mague, Joel T. Acta Crystallogr E Crystallogr Commun Research Communications The product obtained from the reaction of pyridine-2,3-dicarboxylic acid and hydrated copper(II) chloride in hot aqueous NaOH solution was determined by low temperature X-ray diffraction to be [Cu(3)(C(6)H(4)NO(3))(4)(OH)(2)(H(2)O)(2)](n) or [Cu(3)(μ-OH)(2)(μ-nicNO)(4)(H(2)O)(2)](n) (nicNO is pyridine-3-carboxylate N-oxide), a structure obtained from room temperature data and reported previously. The present determination is improved in quality and treatment of the H atoms. A Hirshfeld surface analysis of the intermolecular interactions is presented. International Union of Crystallography 2021-02-26 /pmc/articles/PMC8061101/ /pubmed/33953957 http://dx.doi.org/10.1107/S2056989021002000 Text en © Mirzaei et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Mirzaei, Masoud Bazargan, Maryam Ebtehaj, Pouria Mague, Joel T. A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title | A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title_full | A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title_fullStr | A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title_full_unstemmed | A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title_short | A redetermination of the structure and Hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato N-oxide)tricopper(II)] |
| title_sort | redetermination of the structure and hirshfeld surface analysis of poly[diaquadi-μ-hydroxido-tetrakis(μ-nicotinato n-oxide)tricopper(ii)] |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8061101/ https://www.ncbi.nlm.nih.gov/pubmed/33953957 http://dx.doi.org/10.1107/S2056989021002000 |
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