Structural investigation of N-[2-(4-fluoro-3-phen­oxy­benzo­yl)hydrazinecarbo­thio­yl]benzamide and N-[2-(4-fluoro-3-phen­oxy­benzo­yl)hydrazinecarbo­thio­yl]-4-meth­oxy­benzamide

The compound N-[2-(4-fluoro-3-phen­oxy­benzo­yl)hydrazinecarbo­thio­yl]benzamide, C(21)H(16)FN(3)O(3)S, crystallizes in the monoclinic centrosymmetric space group P2(1)/c and its mol­ecular conformation is stabilized via an intra­molecular N—H⋯O hydrogen bond. The corresponding para-meth­oxy derivat...

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Detalles Bibliográficos
Autores principales: Dey, Dhananjay, Shruti, I., Chopra, Deepak, Mohan, T. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8061111/
https://www.ncbi.nlm.nih.gov/pubmed/33953951
http://dx.doi.org/10.1107/S2056989021001900
Descripción
Sumario:The compound N-[2-(4-fluoro-3-phen­oxy­benzo­yl)hydrazinecarbo­thio­yl]benzamide, C(21)H(16)FN(3)O(3)S, crystallizes in the monoclinic centrosymmetric space group P2(1)/c and its mol­ecular conformation is stabilized via an intra­molecular N—H⋯O hydrogen bond. The corresponding para-meth­oxy derivative, namely, N-[2-(4-fluoro-3-phen­oxy­benzo­yl)hydrazinecarbo­thio­yl]-4-meth­oxy­benzamide, C(22)H(18)FN(3)O(4)S, crystallizes in the monoclinic centrosymmetric space group C2/c. The supra­molecular network mainly comprises N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds, which contribute towards the formation of the crystal structures for the two mol­ecules. The different inter­molecular inter­actions have been further analysed using Hirshfeld surface analysis and fingerprint plots.

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