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Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution

Water is regarded as an important natural resource to sustain life, and its purification is an important criterion that determines its quality and usefulness. In this study, the incorporation of Fe(3+) oxide onto a phenylenediamine (pPD) polymer matrix through chemical co-polymerization was prepared...

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Autores principales: Munzhelele, Elisa Pandelani, Ayinde, Wasiu Babatunde, Mudzielwana, Rabelani, Gitari, Wilson Mugera
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8065817/
https://www.ncbi.nlm.nih.gov/pubmed/33916218
http://dx.doi.org/10.3390/toxics9040074
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author Munzhelele, Elisa Pandelani
Ayinde, Wasiu Babatunde
Mudzielwana, Rabelani
Gitari, Wilson Mugera
author_facet Munzhelele, Elisa Pandelani
Ayinde, Wasiu Babatunde
Mudzielwana, Rabelani
Gitari, Wilson Mugera
author_sort Munzhelele, Elisa Pandelani
collection PubMed
description Water is regarded as an important natural resource to sustain life, and its purification is an important criterion that determines its quality and usefulness. In this study, the incorporation of Fe(3+) oxide onto a phenylenediamine (pPD) polymer matrix through chemical co-polymerization was prepared, and its arsenite and fluoride removal potentials at optimal conditions from aqueous solution were evaluated. The morphology and structural analysis of the synthesized Fe-doped pPD (Fe-pPD) were comparatively evaluated using the FT-IR, SEM, EDS, and XRD techniques. Fe was successfully incorporated onto pPD matrix as confirmed by different morphological characterizations. The rate of adsorption of F(−) and As(3+) onto the Fe-pPD composite best followed the pseudo-second-order kinetic model. The experimental data for both As(3+) and F(−) onto the Fe-pPD composite better fit the Freundlich isotherm model at different operating temperatures. Overall, the synthesized composite exhibited a strong affinity towards fluoride uptake (96.6%) than arsenite uptake (71.14%) with a maximum capacity of 6.79 (F(−)) and 1.86 (As(3+)) mg/g. Additionally, the synthesized adsorbent showed some level of antimicrobial activity against common water-borne bacterial. Therefore, the Fe-doped pPD composite has the potential ability for inorganic metal species pollutants remediation and bacterial disinfection in community-level water purification processes.
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spelling pubmed-80658172021-04-25 Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution Munzhelele, Elisa Pandelani Ayinde, Wasiu Babatunde Mudzielwana, Rabelani Gitari, Wilson Mugera Toxics Article Water is regarded as an important natural resource to sustain life, and its purification is an important criterion that determines its quality and usefulness. In this study, the incorporation of Fe(3+) oxide onto a phenylenediamine (pPD) polymer matrix through chemical co-polymerization was prepared, and its arsenite and fluoride removal potentials at optimal conditions from aqueous solution were evaluated. The morphology and structural analysis of the synthesized Fe-doped pPD (Fe-pPD) were comparatively evaluated using the FT-IR, SEM, EDS, and XRD techniques. Fe was successfully incorporated onto pPD matrix as confirmed by different morphological characterizations. The rate of adsorption of F(−) and As(3+) onto the Fe-pPD composite best followed the pseudo-second-order kinetic model. The experimental data for both As(3+) and F(−) onto the Fe-pPD composite better fit the Freundlich isotherm model at different operating temperatures. Overall, the synthesized composite exhibited a strong affinity towards fluoride uptake (96.6%) than arsenite uptake (71.14%) with a maximum capacity of 6.79 (F(−)) and 1.86 (As(3+)) mg/g. Additionally, the synthesized adsorbent showed some level of antimicrobial activity against common water-borne bacterial. Therefore, the Fe-doped pPD composite has the potential ability for inorganic metal species pollutants remediation and bacterial disinfection in community-level water purification processes. MDPI 2021-04-01 /pmc/articles/PMC8065817/ /pubmed/33916218 http://dx.doi.org/10.3390/toxics9040074 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Munzhelele, Elisa Pandelani
Ayinde, Wasiu Babatunde
Mudzielwana, Rabelani
Gitari, Wilson Mugera
Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title_full Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title_fullStr Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title_full_unstemmed Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title_short Synthesis of Fe Doped Poly p-Phenylenediamine Composite: Co-Adsorption Application on Toxic Metal Ions (F(−) and As(3+)) and Microbial Disinfection in Aqueous Solution
title_sort synthesis of fe doped poly p-phenylenediamine composite: co-adsorption application on toxic metal ions (f(−) and as(3+)) and microbial disinfection in aqueous solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8065817/
https://www.ncbi.nlm.nih.gov/pubmed/33916218
http://dx.doi.org/10.3390/toxics9040074
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