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Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application

Investigation of the collaborative effect of cerium particles embedded in graphene oxide to enhance the chemical stability of a proton exchange membrane fuel cell (PEMFC) has been carried out. Synthesis of composite membranes (Nafion-GO/Ce-x) with Nafion solution as a polymer is synthesized by a sol...

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Autores principales: Sharma, Prem P., Tinh, Vo Dinh Cong, Kim, Dukjoon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8067057/
https://www.ncbi.nlm.nih.gov/pubmed/33800616
http://dx.doi.org/10.3390/membranes11040238
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author Sharma, Prem P.
Tinh, Vo Dinh Cong
Kim, Dukjoon
author_facet Sharma, Prem P.
Tinh, Vo Dinh Cong
Kim, Dukjoon
author_sort Sharma, Prem P.
collection PubMed
description Investigation of the collaborative effect of cerium particles embedded in graphene oxide to enhance the chemical stability of a proton exchange membrane fuel cell (PEMFC) has been carried out. Synthesis of composite membranes (Nafion-GO/Ce-x) with Nafion solution as a polymer is synthesized by a solution casting method where (x = concentration of composite). The developed hybrid material was characterized by FT-IR and X-ray diffraction (XRD) for its phase identification while the chemical structure was characterized by XPS analysis. The enhancement in the chemical stability of the incorporated hybrid material is characterized by Fenton’s test showing a radical scavenging effect. It was found that the residual weight for Nafion (212) was 92.50% after 24 h and it was 94.32% for Nafion-GO/Ce-2 and 96.49% for Nafion-GO/Ce-4, proving the suitability of composite membranes for fuel cell applications.
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spelling pubmed-80670572021-04-25 Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application Sharma, Prem P. Tinh, Vo Dinh Cong Kim, Dukjoon Membranes (Basel) Article Investigation of the collaborative effect of cerium particles embedded in graphene oxide to enhance the chemical stability of a proton exchange membrane fuel cell (PEMFC) has been carried out. Synthesis of composite membranes (Nafion-GO/Ce-x) with Nafion solution as a polymer is synthesized by a solution casting method where (x = concentration of composite). The developed hybrid material was characterized by FT-IR and X-ray diffraction (XRD) for its phase identification while the chemical structure was characterized by XPS analysis. The enhancement in the chemical stability of the incorporated hybrid material is characterized by Fenton’s test showing a radical scavenging effect. It was found that the residual weight for Nafion (212) was 92.50% after 24 h and it was 94.32% for Nafion-GO/Ce-2 and 96.49% for Nafion-GO/Ce-4, proving the suitability of composite membranes for fuel cell applications. MDPI 2021-03-28 /pmc/articles/PMC8067057/ /pubmed/33800616 http://dx.doi.org/10.3390/membranes11040238 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) ).
spellingShingle Article
Sharma, Prem P.
Tinh, Vo Dinh Cong
Kim, Dukjoon
Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title_full Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title_fullStr Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title_full_unstemmed Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title_short Improved Oxidative Stability by Embedded Cerium into Graphene Oxide Nanosheets for Proton Exchange Membrane Fuel Cell Application
title_sort improved oxidative stability by embedded cerium into graphene oxide nanosheets for proton exchange membrane fuel cell application
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8067057/
https://www.ncbi.nlm.nih.gov/pubmed/33800616
http://dx.doi.org/10.3390/membranes11040238
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AT kimdukjoon improvedoxidativestabilitybyembeddedceriumintographeneoxidenanosheetsforprotonexchangemembranefuelcellapplication