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Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties

This report shows a simple solution cast methodology to prepare plasticized polyvinyl alcohol (PVA)/methylcellulose (MC)-ammonium iodide (NH(4)I) electrolyte at room temperature. The maximum conducting membrane has a conductivity of 3.21 × 10(−3) S/cm. It is shown that the number density, mobility a...

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Autores principales: Aziz, Shujahadeen B., Nofal, Muaffaq M., Kadir, M. F. Z., Dannoun, Elham M. A., Brza, Mohamad A., Hadi, Jihad M., Abdullah, Ranjdar M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8074153/
https://www.ncbi.nlm.nih.gov/pubmed/33923484
http://dx.doi.org/10.3390/ma14081994
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author Aziz, Shujahadeen B.
Nofal, Muaffaq M.
Kadir, M. F. Z.
Dannoun, Elham M. A.
Brza, Mohamad A.
Hadi, Jihad M.
Abdullah, Ranjdar M.
author_facet Aziz, Shujahadeen B.
Nofal, Muaffaq M.
Kadir, M. F. Z.
Dannoun, Elham M. A.
Brza, Mohamad A.
Hadi, Jihad M.
Abdullah, Ranjdar M.
author_sort Aziz, Shujahadeen B.
collection PubMed
description This report shows a simple solution cast methodology to prepare plasticized polyvinyl alcohol (PVA)/methylcellulose (MC)-ammonium iodide (NH(4)I) electrolyte at room temperature. The maximum conducting membrane has a conductivity of 3.21 × 10(−3) S/cm. It is shown that the number density, mobility and diffusion coefficient of ions are enhanced by increasing the glycerol. A number of electric and electrochemical properties of the electrolyte—impedance, dielectric properties, transference numbers, potential window, energy density, specific capacitance (C(s)) and power density—were determined. From the determined electric and electrochemical properties, it is shown that PVA: MC-NH(4)I proton conducting polymer electrolyte (PE) is adequate for utilization in energy storage device (ESD). The decrease of charge transfer resistance with increasing plasticizer was observed from Bode plot. The analysis of dielectric properties has indicated that the plasticizer is a novel approach to increase the number of charge carriers. The electron and ion transference numbers were found. From the linear sweep voltammetry (LSV) response, the breakdown voltage of the electrolyte is determined. From Galvanostatic charge-discharge (GCD) measurement, the calculated C(s) values are found to drop with increasing the number of cycles. The increment of internal resistance is shown by equivalent series resistance (ESR) plot. The energy and power density were studied over 250 cycles that results to the value of 5.38–3.59 Wh/kg and 757.58–347.22 W/kg, respectively.
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spelling pubmed-80741532021-04-27 Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties Aziz, Shujahadeen B. Nofal, Muaffaq M. Kadir, M. F. Z. Dannoun, Elham M. A. Brza, Mohamad A. Hadi, Jihad M. Abdullah, Ranjdar M. Materials (Basel) Article This report shows a simple solution cast methodology to prepare plasticized polyvinyl alcohol (PVA)/methylcellulose (MC)-ammonium iodide (NH(4)I) electrolyte at room temperature. The maximum conducting membrane has a conductivity of 3.21 × 10(−3) S/cm. It is shown that the number density, mobility and diffusion coefficient of ions are enhanced by increasing the glycerol. A number of electric and electrochemical properties of the electrolyte—impedance, dielectric properties, transference numbers, potential window, energy density, specific capacitance (C(s)) and power density—were determined. From the determined electric and electrochemical properties, it is shown that PVA: MC-NH(4)I proton conducting polymer electrolyte (PE) is adequate for utilization in energy storage device (ESD). The decrease of charge transfer resistance with increasing plasticizer was observed from Bode plot. The analysis of dielectric properties has indicated that the plasticizer is a novel approach to increase the number of charge carriers. The electron and ion transference numbers were found. From the linear sweep voltammetry (LSV) response, the breakdown voltage of the electrolyte is determined. From Galvanostatic charge-discharge (GCD) measurement, the calculated C(s) values are found to drop with increasing the number of cycles. The increment of internal resistance is shown by equivalent series resistance (ESR) plot. The energy and power density were studied over 250 cycles that results to the value of 5.38–3.59 Wh/kg and 757.58–347.22 W/kg, respectively. MDPI 2021-04-16 /pmc/articles/PMC8074153/ /pubmed/33923484 http://dx.doi.org/10.3390/ma14081994 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Aziz, Shujahadeen B.
Nofal, Muaffaq M.
Kadir, M. F. Z.
Dannoun, Elham M. A.
Brza, Mohamad A.
Hadi, Jihad M.
Abdullah, Ranjdar M.
Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title_full Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title_fullStr Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title_full_unstemmed Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title_short Bio-Based Plasticized PVA Based Polymer Blend Electrolytes for Energy Storage EDLC Devices: Ion Transport Parameters and Electrochemical Properties
title_sort bio-based plasticized pva based polymer blend electrolytes for energy storage edlc devices: ion transport parameters and electrochemical properties
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8074153/
https://www.ncbi.nlm.nih.gov/pubmed/33923484
http://dx.doi.org/10.3390/ma14081994
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