Cargando…
Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions
The homolytic cleavage of the P(V)(O)–P(III) bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective...
Autores principales: | Tran, Dat Phuc, Sato, Yuki, Yamamoto, Yuki, Kawaguchi, Shin-ichi, Kodama, Shintaro, Nomoto, Akihiro, Ogawa, Akiya |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8077611/ https://www.ncbi.nlm.nih.gov/pubmed/33968259 http://dx.doi.org/10.3762/bjoc.17.72 |
Ejemplares similares
-
Photoinduced Bisphosphination of Alkynes with Phosphorus Interelement Compounds and Its Application to Double-Bond Isomerization
por: Yamamoto, Yuki, et al.
Publicado: (2022) -
Regio- and Stereoselective Radical Perfluoroalkyltriflation
of Alkynes Using Phenyl(perfluoroalkyl)iodonium
Triflates
por: Wang, Xi, et al.
Publicado: (2017) -
Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via S(H)2 Reaction of Aryl Radicals on Tellurium
por: Yamamoto, Yuki, et al.
Publicado: (2022) -
Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective
Hydrocarboxylation of Internal Alkynes
por: Dupuy, Stéphanie, et al.
Publicado: (2015) -
Regio- and stereoselective thiocyanatothiolation of alkynes and alkenes by using NH(4)SCN and N-thiosuccinimides
por: Qi, Liang, et al.
Publicado: (2020)