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Manganese/bipyridine-catalyzed non-directed C(sp(3))–H bromination using NBS and TMSN(3)

A Mn(II)/bipyridine-catalyzed bromination reaction of unactivated aliphatic C(sp(3))−H bonds has been developed using N-bromosuccinimide (NBS) as the brominating reagent. The reaction proceeded in moderate-to-good yield, even on a gram scale. The introduced bromine atom can be converted into fluorin...

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Detalles Bibliográficos
Autores principales:	Sneh, Kumar, Torigoe, Takeru, Kuninobu, Yoichiro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2021
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8077618/ https://www.ncbi.nlm.nih.gov/pubmed/33968261 http://dx.doi.org/10.3762/bjoc.17.74

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