One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening

The synthesis of pure difunctionalized hexa‐, hepta‐ and octamaltosides was performed by one‐pot chemical reaction from perbenzoylated cyclodextrin. Oligomaltosides with azide, propargyl or allyl on reducing end and an unprotected hydroxyl group on non‐reducing end were obtained from perbenzoylated...

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Autores principales: Pélingre, Matthieu, Smadhi, Meriem, Bil, Abed, Bonnet, Véronique, Kovensky, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8080284/
https://www.ncbi.nlm.nih.gov/pubmed/33908706
http://dx.doi.org/10.1002/open.202100079
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author Pélingre, Matthieu
Smadhi, Meriem
Bil, Abed
Bonnet, Véronique
Kovensky, José
author_facet Pélingre, Matthieu
Smadhi, Meriem
Bil, Abed
Bonnet, Véronique
Kovensky, José
author_sort Pélingre, Matthieu
collection PubMed
description The synthesis of pure difunctionalized hexa‐, hepta‐ and octamaltosides was performed by one‐pot chemical reaction from perbenzoylated cyclodextrin. Oligomaltosides with azide, propargyl or allyl on reducing end and an unprotected hydroxyl group on non‐reducing end were obtained from perbenzoylated α‐, β‐ and γ‐cyclodextrin with 12 to 48 % yields.
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spelling pubmed-80802842021-05-05 One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening Pélingre, Matthieu Smadhi, Meriem Bil, Abed Bonnet, Véronique Kovensky, José ChemistryOpen Communications The synthesis of pure difunctionalized hexa‐, hepta‐ and octamaltosides was performed by one‐pot chemical reaction from perbenzoylated cyclodextrin. Oligomaltosides with azide, propargyl or allyl on reducing end and an unprotected hydroxyl group on non‐reducing end were obtained from perbenzoylated α‐, β‐ and γ‐cyclodextrin with 12 to 48 % yields. John Wiley and Sons Inc. 2021-04-28 /pmc/articles/PMC8080284/ /pubmed/33908706 http://dx.doi.org/10.1002/open.202100079 Text en © 2021 The Authors. Published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Pélingre, Matthieu
Smadhi, Meriem
Bil, Abed
Bonnet, Véronique
Kovensky, José
One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title_full One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title_fullStr One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title_full_unstemmed One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title_short One‐Pot Synthesis of Asymmetrically Difunctionalized Oligomaltosides by Cyclodextrin Ring Opening
title_sort one‐pot synthesis of asymmetrically difunctionalized oligomaltosides by cyclodextrin ring opening
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8080284/
https://www.ncbi.nlm.nih.gov/pubmed/33908706
http://dx.doi.org/10.1002/open.202100079
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