Synthesis of Tetra‐Substituted Trifluoromethyl‐3,1‐Benzoxazines by Transition‐Metal‐Catalyzed Decarboxylative Cyclization of N‐Benzoyl Benzoxazinones

Efficient synthesis of N,O‐heterocyclic tetra‐substituted trifluoromethyl‐3,1‐benzoxazines via a transition‐metal‐catalyzed decarboxylative intramolecular cyclization was achieved. The decarboxylation of N‐benzoyl trifluoromethyl‐benzoxazinones generated the amide oxygen nucleophile, allowing a sele...

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Detalles Bibliográficos
Autores principales: Uno, Hiroto, Fujimoto, Daichi, Harada, Kyosuke, Tanaka, Chika, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8095294/
https://www.ncbi.nlm.nih.gov/pubmed/33605087
http://dx.doi.org/10.1002/open.202000360

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8095294/
https://www.ncbi.nlm.nih.gov/pubmed/33605087
http://dx.doi.org/10.1002/open.202000360

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