Kesterite Solar Cells: Insights into Current Strategies and Challenges

Earth‐abundant and environmentally benign kesterite Cu(2)ZnSn(S,Se)(4) (CZTSSe) is a promising alternative to its cousin chalcopyrite Cu(In,Ga)(S,Se)(2) (CIGS) for photovoltaic applications. However, the power conversion efficiency of CZTSSe solar cells has been stagnant at 12.6% for years, still far lower than that of CIGS (23.35%). In this report, insights into the latest cutting‐edge strategies for further advance in the performance of kesterite solar cells is provided, particularly focusing on the postdeposition thermal treatment (for bare absorber, heterojunction, and completed device), alkali doping, and bandgap grading by engineering graded cation and/or anion alloying. These strategies, which have led to the step‐change improvements in the power conversion efficiency of the counterpart CIGS solar cells, are also the most promising ones to achieve further efficiency breakthroughs for kesterite solar cells. Herein, the recent advances in kesterite solar cells along these pathways are reviewed, and more importantly, a comprehensive understanding of the underlying mechanisms is provided, and promising directions for the ongoing development of kesterite solar cells are proposed.