Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)

In the title complex, [Sm(NO(3))(3)(C(30)H(28)N(2)O(4))], the Sm atom is surrounded by ten O atoms. The (S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolate) ligand, obtained from o-vanillin and (1S,2S)-(−)-1,2-di­phenyl­ethyl­enedi­amine,...

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Autores principales: Okumura, Yuta, Takiguchi, Yuji, Nakane, Daisuke, Akitsu, Takashiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100257/
https://www.ncbi.nlm.nih.gov/pubmed/34026269
http://dx.doi.org/10.1107/S2056989021004424
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author Okumura, Yuta
Takiguchi, Yuji
Nakane, Daisuke
Akitsu, Takashiro
author_facet Okumura, Yuta
Takiguchi, Yuji
Nakane, Daisuke
Akitsu, Takashiro
author_sort Okumura, Yuta
collection PubMed
description In the title complex, [Sm(NO(3))(3)(C(30)H(28)N(2)O(4))], the Sm atom is surrounded by ten O atoms. The (S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolate) ligand, obtained from o-vanillin and (1S,2S)-(−)-1,2-di­phenyl­ethyl­enedi­amine, exhibits a slightly distorted planar arrangement of the four coordinated O atoms. In the crystal, the complex shows intra­molecular N—H⋯O hydrogen bonds and weak inter­molecular C—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (33.5%), O⋯H (34.1%) and C⋯H (21.7%) contacts.
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spelling pubmed-81002572021-05-21 Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III) Okumura, Yuta Takiguchi, Yuji Nakane, Daisuke Akitsu, Takashiro Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [Sm(NO(3))(3)(C(30)H(28)N(2)O(4))], the Sm atom is surrounded by ten O atoms. The (S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­niumylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolate) ligand, obtained from o-vanillin and (1S,2S)-(−)-1,2-di­phenyl­ethyl­enedi­amine, exhibits a slightly distorted planar arrangement of the four coordinated O atoms. In the crystal, the complex shows intra­molecular N—H⋯O hydrogen bonds and weak inter­molecular C—H⋯O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H⋯H (33.5%), O⋯H (34.1%) and C⋯H (21.7%) contacts. International Union of Crystallography 2021-04-30 /pmc/articles/PMC8100257/ /pubmed/34026269 http://dx.doi.org/10.1107/S2056989021004424 Text en © Okumura et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Okumura, Yuta
Takiguchi, Yuji
Nakane, Daisuke
Akitsu, Takashiro
Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title_full Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title_fullStr Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title_short Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(III)
title_sort crystal structure and hirshfeld surface analysis of ((s,s)-2,2′-{[(1,2-di­phenyl­ethane-1,2-di­yl)bis­[(aza­n­ium­ylyl­idene)methanylyl­idene]}bis­(6-meth­oxy­phenolato))trinitratosamarium(iii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100257/
https://www.ncbi.nlm.nih.gov/pubmed/34026269
http://dx.doi.org/10.1107/S2056989021004424
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