Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide

The title ketenyl­idene, [Au(3)(C(2)O)(C(26)H(35)O(2)P)(3)](C(2)F(6)NO(4)S(2)), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the t...

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Detalles Bibliográficos
Autores principales: Hartgerink, Colin T., Staples, Richard J., Anderson, Carolyn E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100268/
https://www.ncbi.nlm.nih.gov/pubmed/34026260
http://dx.doi.org/10.1107/S2056989021003844
Descripción
Sumario:The title ketenyl­idene, [Au(3)(C(2)O)(C(26)H(35)O(2)P)(3)](C(2)F(6)NO(4)S(2)), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl­idene with atomic distances indicative of bonding inter­action between the gold atoms.

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