Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide

The title ketenyl­idene, [Au(3)(C(2)O)(C(26)H(35)O(2)P)(3)](C(2)F(6)NO(4)S(2)), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the t...

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Detalles Bibliográficos
Autores principales: Hartgerink, Colin T., Staples, Richard J., Anderson, Carolyn E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100268/
https://www.ncbi.nlm.nih.gov/pubmed/34026260
http://dx.doi.org/10.1107/S2056989021003844
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author Hartgerink, Colin T.
Staples, Richard J.
Anderson, Carolyn E.
author_facet Hartgerink, Colin T.
Staples, Richard J.
Anderson, Carolyn E.
author_sort Hartgerink, Colin T.
collection PubMed
description The title ketenyl­idene, [Au(3)(C(2)O)(C(26)H(35)O(2)P)(3)](C(2)F(6)NO(4)S(2)), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl­idene with atomic distances indicative of bonding inter­action between the gold atoms.
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spelling pubmed-81002682021-05-21 Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide Hartgerink, Colin T. Staples, Richard J. Anderson, Carolyn E. Acta Crystallogr E Crystallogr Commun Research Communications The title ketenyl­idene, [Au(3)(C(2)O)(C(26)H(35)O(2)P)(3)](C(2)F(6)NO(4)S(2)), was obtained upon exposure of [2-(di­cyclo­hexyl­phosphino)-2′,6′-dimeth­oxy-1,1′-biphen­yl]gold(I) bis­(tri­fluoro­methane­sulfon­yl)imide to acetic anhydride at elevated temperature. The ketenyl­idene bridge caps the tri-gold cluster. The title compound has provided crystals that upon analysis represent the first tri-gold ketenyl­idene with atomic distances indicative of bonding inter­action between the gold atoms. International Union of Crystallography 2021-04-16 /pmc/articles/PMC8100268/ /pubmed/34026260 http://dx.doi.org/10.1107/S2056989021003844 Text en © Hartgerink et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Hartgerink, Colin T.
Staples, Richard J.
Anderson, Carolyn E.
Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title_full Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title_fullStr Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title_full_unstemmed Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title_short Crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κP)-μ-oxoethenyl­idene-triangulo-trigold(I) bis­(tri­fluoro­methane­sulfon­yl)imide
title_sort crystal structure of tris­(2-di­cyclo­hexyl­phosphino-2′,6′-dimeth­oxy-1,1′-biphenyl-κp)-μ-oxoethenyl­idene-triangulo-trigold(i) bis­(tri­fluoro­methane­sulfon­yl)imide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100268/
https://www.ncbi.nlm.nih.gov/pubmed/34026260
http://dx.doi.org/10.1107/S2056989021003844
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AT staplesrichardj crystalstructureoftris2dicyclohexylphosphino26dimethoxy11biphenylkpmoxoethenylidenetriangulotrigoldibistrifluoromethanesulfonylimide
AT andersoncarolyne crystalstructureoftris2dicyclohexylphosphino26dimethoxy11biphenylkpmoxoethenylidenetriangulotrigoldibistrifluoromethanesulfonylimide

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