Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate

The title compound, [ZnCl(2)(C(13)H(11)N(3))]·C(3)H(7)NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex mol­ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di­methyl­formamide monosolvate....

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Detalles Bibliográficos
Autores principales: Muslim, Mohd, Faizi, Md. Serajul Haque, Ali, Arif, Afzal, Mohd, Ahmad, Musheer, Dege, Necmi, Mashrai, Ashraf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100270/
https://www.ncbi.nlm.nih.gov/pubmed/34026251
http://dx.doi.org/10.1107/S2056989021003649
Descripción
Sumario:The title compound, [ZnCl(2)(C(13)H(11)N(3))]·C(3)H(7)NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex mol­ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di­methyl­formamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetra­hedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N—H⋯O, N—H⋯Cl, C—H⋯Cl hydrogen bonding.

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