Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate

The title compound, [ZnCl(2)(C(13)H(11)N(3))]·C(3)H(7)NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex mol­ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di­methyl­formamide monosolvate....

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Autores principales: Muslim, Mohd, Faizi, Md. Serajul Haque, Ali, Arif, Afzal, Mohd, Ahmad, Musheer, Dege, Necmi, Mashrai, Ashraf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100270/
https://www.ncbi.nlm.nih.gov/pubmed/34026251
http://dx.doi.org/10.1107/S2056989021003649
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author Muslim, Mohd
Faizi, Md. Serajul Haque
Ali, Arif
Afzal, Mohd
Ahmad, Musheer
Dege, Necmi
Mashrai, Ashraf
author_facet Muslim, Mohd
Faizi, Md. Serajul Haque
Ali, Arif
Afzal, Mohd
Ahmad, Musheer
Dege, Necmi
Mashrai, Ashraf
author_sort Muslim, Mohd
collection PubMed
description The title compound, [ZnCl(2)(C(13)H(11)N(3))]·C(3)H(7)NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex mol­ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di­methyl­formamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetra­hedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N—H⋯O, N—H⋯Cl, C—H⋯Cl hydrogen bonding.
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spelling pubmed-81002702021-05-21 Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate Muslim, Mohd Faizi, Md. Serajul Haque Ali, Arif Afzal, Mohd Ahmad, Musheer Dege, Necmi Mashrai, Ashraf Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [ZnCl(2)(C(13)H(11)N(3))]·C(3)H(7)NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex mol­ecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with di­methyl­formamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetra­hedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N—H⋯O, N—H⋯Cl, C—H⋯Cl hydrogen bonding. International Union of Crystallography 2021-04-09 /pmc/articles/PMC8100270/ /pubmed/34026251 http://dx.doi.org/10.1107/S2056989021003649 Text en © Muslim et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Muslim, Mohd
Faizi, Md. Serajul Haque
Ali, Arif
Afzal, Mohd
Ahmad, Musheer
Dege, Necmi
Mashrai, Ashraf
Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title_full Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title_fullStr Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title_short Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]di­chlorido­zinc(II) N,N-di­methyl­formamide monosolvate
title_sort crystal structure and hirshfeld surface analysis of [2-(1h-benzimidazol-2-yl-κn (3))aniline-κn]di­chlorido­zinc(ii) n,n-di­methyl­formamide monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100270/
https://www.ncbi.nlm.nih.gov/pubmed/34026251
http://dx.doi.org/10.1107/S2056989021003649
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