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Crystal structure and Hirshfeld surface analysis of 4,5-di­bromo-2-(4-meth­oxy­phen­yl)-2,3,4,4a,5,6,7,7a-octa­hydro-1H-4,6-ep­oxy-1H-cyclo­penta­[c]pyridin-1-one

The mol­ecule of the title compound, C(15)H(15)Br(2)NO(3), comprises a fused tricyclic system consisting of two five-membered rings (cyclo­pentane and tetra­hydro­furan) and one six-membered ring (tetra­hydro­pyridinone). Both five-membered rings of the tricyclic system have envelope conformations,...

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Detalles Bibliográficos
Autores principales: Mertsalov, Dmitriy F., Surina, Nataliya S., Sorokina, Elena A., Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Grigoriev, Mikhail S., Mlowe, Sixberth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8100279/
https://www.ncbi.nlm.nih.gov/pubmed/34026259
http://dx.doi.org/10.1107/S2056989021003273
Descripción
Sumario:The mol­ecule of the title compound, C(15)H(15)Br(2)NO(3), comprises a fused tricyclic system consisting of two five-membered rings (cyclo­pentane and tetra­hydro­furan) and one six-membered ring (tetra­hydro­pyridinone). Both five-membered rings of the tricyclic system have envelope conformations, and the conformation of the six-membered cycle is inter­mediate between chair and half-chair. In the crystal, the mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π, C—Br⋯π and C⋯O inter­actions into double layers. The layers are connected into a three-dimensional network by van der Waals inter­actions.