Cargando…

Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium

The simultaneous removal of mixed containments of antibiotics and heavy metals is still a big challenge in wastewater treatment. Herein, we report the successful synthesis of N-doped porous carbon (abbreviated as NC) from straw waste through the Maillard reaction to activate sp(3)-sp(2) conversion e...

Descripción completa

Detalles Bibliográficos
Autores principales: Yan, Kai, Li, Ruiqi, Yang, Zhiyu, Li, Xin, Wang, Yuchen, Wu, Guosheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8105648/
https://www.ncbi.nlm.nih.gov/pubmed/33997699
http://dx.doi.org/10.1016/j.isci.2021.102421
_version_ 1783689644171329536
author Yan, Kai
Li, Ruiqi
Yang, Zhiyu
Li, Xin
Wang, Yuchen
Wu, Guosheng
author_facet Yan, Kai
Li, Ruiqi
Yang, Zhiyu
Li, Xin
Wang, Yuchen
Wu, Guosheng
author_sort Yan, Kai
collection PubMed
description The simultaneous removal of mixed containments of antibiotics and heavy metals is still a big challenge in wastewater treatment. Herein, we report the successful synthesis of N-doped porous carbon (abbreviated as NC) from straw waste through the Maillard reaction to activate sp(3)-sp(2) conversion efficient for the simultaneous removal of chlortetracycline (CTC) and hexavalent chromium (Cr(VI)). In 200 min, 96.9% of Cr(VI) was reduced into Cr(III) and 93.1% of CTC was oxidatively degraded. Reactive substances (e.g., h(+), e(−1), ⋅OH, and ⋅O(2)(-)) were verified for the photocatalytic reactions. Besides, the possible degradation intermediates of CTC were analyzed with ultra performance liquid chromatography-mass spectrometry (UPLC-MS/MS), and the mechanism of photocatalytic degradation of CTC was then proposed. The synthesized bifunctional NC materials could also be applied for the similar system; this will open the door for promising practical applications.
format Online
Article
Text
id pubmed-8105648
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher Elsevier
record_format MEDLINE/PubMed
spelling pubmed-81056482021-05-14 Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium Yan, Kai Li, Ruiqi Yang, Zhiyu Li, Xin Wang, Yuchen Wu, Guosheng iScience Article The simultaneous removal of mixed containments of antibiotics and heavy metals is still a big challenge in wastewater treatment. Herein, we report the successful synthesis of N-doped porous carbon (abbreviated as NC) from straw waste through the Maillard reaction to activate sp(3)-sp(2) conversion efficient for the simultaneous removal of chlortetracycline (CTC) and hexavalent chromium (Cr(VI)). In 200 min, 96.9% of Cr(VI) was reduced into Cr(III) and 93.1% of CTC was oxidatively degraded. Reactive substances (e.g., h(+), e(−1), ⋅OH, and ⋅O(2)(-)) were verified for the photocatalytic reactions. Besides, the possible degradation intermediates of CTC were analyzed with ultra performance liquid chromatography-mass spectrometry (UPLC-MS/MS), and the mechanism of photocatalytic degradation of CTC was then proposed. The synthesized bifunctional NC materials could also be applied for the similar system; this will open the door for promising practical applications. Elsevier 2021-04-12 /pmc/articles/PMC8105648/ /pubmed/33997699 http://dx.doi.org/10.1016/j.isci.2021.102421 Text en © 2021 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Yan, Kai
Li, Ruiqi
Yang, Zhiyu
Li, Xin
Wang, Yuchen
Wu, Guosheng
Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title_full Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title_fullStr Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title_full_unstemmed Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title_short Biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
title_sort biomass waste-derived porous carbon efficient for simultaneous removal of chlortetracycline and hexavalent chromium
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8105648/
https://www.ncbi.nlm.nih.gov/pubmed/33997699
http://dx.doi.org/10.1016/j.isci.2021.102421
work_keys_str_mv AT yankai biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium
AT liruiqi biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium
AT yangzhiyu biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium
AT lixin biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium
AT wangyuchen biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium
AT wuguosheng biomasswastederivedporouscarbonefficientforsimultaneousremovalofchlortetracyclineandhexavalentchromium