Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces

We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates.

Detalles Bibliográficos
Autores principales: Nemat, Suren J., Van den Eynden, Dietger, Deblock, Loren, Heilmann, Michael, Köster, Jesper M., Parvizian, Mahsa, Tiefenbacher, Konrad, De Roo, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8112235/
https://www.ncbi.nlm.nih.gov/pubmed/33977984
http://dx.doi.org/10.1039/d1cc00223f
Descripción
Sumario:We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates.

Ejemplares similares