Cargando…

Iterative Exponential Growth of Oxygen-Linked Aromatic Polymers Driven by Nucleophilic Aromatic Substitution Reactions

This work presents the first transition metal-free synthesis of oxygen-linked aromatic polymers by integrating iterative exponential polymer growth (IEG) with nucleophilic aromatic substitution (S(N)Ar) reactions. Our approach applies methyl sulfones as the leaving groups, which eliminate the need f...

Descripción completa

Detalles Bibliográficos
Autores principales:	Jaynes, Tyler J., Sharafi, Mona, Campbell, Joseph P., Bocanegra, Jessica, McKay, Kyle T., Little, Kassondra, Osadchey Brown, Reilly, Gray, Danielle L., Woods, Toby J., Li, Jianing, Schneebeli, Severin T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Frontiers Media S.A. 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8113702/ https://www.ncbi.nlm.nih.gov/pubmed/33996739 http://dx.doi.org/10.3389/fchem.2021.620017

Ejemplares similares

Concerted Nucleophilic Aromatic Substitutions
por: Kwan, Eugene E., et al.
Publicado: (2018)

Precise through-space control of an abiotic electrophilic aromatic substitution reaction
por: Murphy, Kyle E., et al.
Publicado: (2017)

Concerted Nucleophilic Aromatic Substitution Reactions
por: Rohrbach, Simon, et al.
Publicado: (2019)

Dynamic Nucleophilic Aromatic Substitution of Tetrazines
por: Santos, Tanausú, et al.
Publicado: (2021)

Transetherification of 2,4-dimethoxynitrobenzene by aromatic nucleophilic substitution
por: Song, Jiho, et al.
Publicado: (2017)

Concerted nucleophilic aromatic substitution with (19)F(−) and (18)F(−)
por: Neumann, Constanze N., et al.
Publicado: (2016)

Utility of certain nucleophilic aromatic substitution reactions for the assay of pregabalin in capsules
por: Walash, Mohamed I, et al.
Publicado: (2011)

How Do Aromatic Nitro Compounds React with Nucleophiles? Theoretical Description Using Aromaticity, Nucleophilicity and Electrophilicity Indices
por: Błaziak, Kacper, et al.
Publicado: (2020)

Utilizing the σ-complex stability for quantifying reactivity in nucleophilic substitution of aromatic fluorides
por: Liljenberg, Magnus, et al.
Publicado: (2013)

Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives
por: Kikushima, Kotaro, et al.
Publicado: (2021)

Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene
por: Ajenjo, Javier, et al.
Publicado: (2016)

A Greener and Efficient Method for Nucleophilic Aromatic Substitution of Nitrogen-Containing Fused Heterocycles
por: Campos, Joana F., et al.
Publicado: (2018)

Nucleophilic Aromatic Substitution (S(N)Ar) and Related Reactions of Porphyrinoids: Mechanistic and Regiochemical Aspects
por: Sample, Harry C., et al.
Publicado: (2020)

Nucleophilic Aromatic Substitution of Pentafluorophenyl-Substituted Quinoline with a Functional Perylene: A Route to the Modification of Semiconducting Polymers
por: Aivali, Stefania, et al.
Publicado: (2023)

Validated spectrophotometric methods for determination of Alendronate sodium in tablets through nucleophilic aromatic substitution reactions
por: Walash, Mohamed I, et al.
Publicado: (2012)

Direct synthesis of covalent triazine-based frameworks (CTFs) through aromatic nucleophilic substitution reactions
por: Chen, Tao, et al.
Publicado: (2019)

C(sp(3))-Arylation by Conformationally Accelerated Intramolecular Nucleophilic Aromatic Substitution (S(N)Ar)
por: Wales, Steven M., et al.
Publicado: (2022)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

Intra- versus intermolecular electron transfer in radical nucleophilic aromatic substitution of dihalo(hetero)arenes – a tool for estimating π-conjugation in aromatic systems
por: Janhsen, B., et al.
Publicado: (2017)

Synthesis and Late-Stage Functionalization of Complex Molecules through C–H Fluorination and Nucleophilic Aromatic Substitution
por: Fier, Patrick S., et al.
Publicado: (2014)

New Route to Glycosylated Porphyrins via Aromatic Nucleophilic Substitution (S(N)Ar)—Synthesis and Cellular Uptake Studies
por: Rosa, Mariusz, et al.
Publicado: (2022)

Direct Amination of Nitroquinoline Derivatives via Nucleophilic Displacement of Aromatic Hydrogen
por: Wantulok, Jakub, et al.
Publicado: (2021)

Biocatalytic Aromaticity-Breaking Epoxidation of Naphthalene and Nucleophilic Ring-Opening Reactions
por: Zhang, Wuyuan, et al.
Publicado: (2021)

(19)F- and (18)F-Arene Deoxyfluorination via Organic Photoredox-Catalysed Polarity-Reversed Nucleophilic Aromatic Substitution
por: Tay, Nicholas E. S., et al.
Publicado: (2020)

A broadly applicable quantitative relative reactivity model for nucleophilic aromatic substitution (S(N)Ar) using simple descriptors
por: Lu, Jingru, et al.
Publicado: (2022)

Carbonyl-to-Alkyne Electron Donation Effects in up to 10-nm-Long, Unimolecular Oligo(p-phenylene ethynylenes)
por: Rajappan, Sinu C., et al.
Publicado: (2021)

Chemically Recyclable Polymer System Based on Nucleophilic Aromatic Ring-Opening Polymerization
por: Su, Yong-Liang, et al.
Publicado: (2023)

Nucleophilic aromatization of monoterpenes from isoprene under nickel/iodine cascade catalysis
por: Zhang, Wei-Song, et al.
Publicado: (2023)

Fluorescent probes based on nucleophilic aromatic substitution reactions for reactive sulfur and selenium species: Recent progress, applications, and design strategies
por: Liu, Yuning, et al.
Publicado: (2021)

A highly green approach towards aromatic nitro group substitutions: catalyst free reactions of nitroimidazoles with carbon nucleophiles in water
por: Shah, Syed Raza, et al.
Publicado: (2020)

Rational design of a “dual lock-and-key” supramolecular photosensitizer based on aromatic nucleophilic substitution for specific and enhanced photodynamic therapy
por: Teng, Kun-Xu, et al.
Publicado: (2020)

Correction: Rational design of a “dual lock-and-key” supramolecular photosensitizer based on aromatic nucleophilic substitution for specific and enhanced photodynamic therapy
por: Teng, Kun-Xu, et al.
Publicado: (2020)

Synthesis, Characterization, and Environmental Applications of Novel Per-Fluorinated Organic Polymers with Azo- and Azomethine-Based Linkers via Nucleophilic Aromatic Substitution
por: Altarawneh, Suha S., et al.
Publicado: (2023)

The double protonation of dihapto-coordinated benzene complexes enables dearomatization using aromatic nucleophiles
por: Weatherford-Pratt, Justin T., et al.
Publicado: (2023)

Efficient one-pot synthesis of functionalised imidazo[1,2-a]pyridines and unexpected synthesis of novel tetracyclic derivatives by nucleophilic aromatic substitution
por: Changunda, Charles R. K., et al.
Publicado: (2020)

4-Trifluoromethyl-p-quinols as dielectrophiles: three-component, double nucleophilic addition/aromatization reactions
por: Dong, Jinhuan, et al.
Publicado: (2016)

The Double-Protonation of Dihapto-Coordinated Benzene Complexes: An Enabling Strategy for Dearomatization Using Aromatic Nucleophiles
por: Smith, Jacob, et al.
Publicado: (2023)

Effect of Aromatic Substitution of Curcumin Nanoformulations on Their Stability
por: Okonogi, Siriporn, et al.
Publicado: (2016)

Energetics of Electron Pairs in Electrophilic Aromatic Substitutions
por: Munárriz, Julen, et al.
Publicado: (2021)

Making Aromatic Phosphorus Heterocycles More Basic and Nucleophilic: Synthesis, Characterization and Reactivity of the First Phosphinine Selenide
por: Wossidlo, Friedrich, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_ullpffjtnb3ae4dq6gnrjvu9eq