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Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene

Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NM...

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Autores principales: Dong, Zhaowen, Winkler, Jan Mathis, Schmidtmann, Marc, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/
https://www.ncbi.nlm.nih.gov/pubmed/34084426
http://dx.doi.org/10.1039/d1sc00956g
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author Dong, Zhaowen
Winkler, Jan Mathis
Schmidtmann, Marc
Müller, Thomas
author_facet Dong, Zhaowen
Winkler, Jan Mathis
Schmidtmann, Marc
Müller, Thomas
author_sort Dong, Zhaowen
collection PubMed
description Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NMR spectroscopy and, in one case, the formal dimer, 2,4-disila-1λ(3),3λ(3)-digermetane, was isolated. The main products of these reactions are sila-bis-λ(3)-germiranes, i.e. directly interconnected digermylenes that are part of a three-membered ring. The structural data, supported by the results of density functional calculations confirm the digermylene nature of these products with a long inner cyclic Ge–Ge bond that decreases the inherent high ring strain in silagermiranes.
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spelling pubmed-81151062021-06-02 Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene Dong, Zhaowen Winkler, Jan Mathis Schmidtmann, Marc Müller, Thomas Chem Sci Chemistry Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NMR spectroscopy and, in one case, the formal dimer, 2,4-disila-1λ(3),3λ(3)-digermetane, was isolated. The main products of these reactions are sila-bis-λ(3)-germiranes, i.e. directly interconnected digermylenes that are part of a three-membered ring. The structural data, supported by the results of density functional calculations confirm the digermylene nature of these products with a long inner cyclic Ge–Ge bond that decreases the inherent high ring strain in silagermiranes. The Royal Society of Chemistry 2021-03-22 /pmc/articles/PMC8115106/ /pubmed/34084426 http://dx.doi.org/10.1039/d1sc00956g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Dong, Zhaowen
Winkler, Jan Mathis
Schmidtmann, Marc
Müller, Thomas
Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title_full Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title_fullStr Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title_full_unstemmed Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title_short Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
title_sort three-membered cyclic digermylenes stabilised by an n-heterocyclic carbene
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/
https://www.ncbi.nlm.nih.gov/pubmed/34084426
http://dx.doi.org/10.1039/d1sc00956g
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