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Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NM...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/ https://www.ncbi.nlm.nih.gov/pubmed/34084426 http://dx.doi.org/10.1039/d1sc00956g |
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author | Dong, Zhaowen Winkler, Jan Mathis Schmidtmann, Marc Müller, Thomas |
author_facet | Dong, Zhaowen Winkler, Jan Mathis Schmidtmann, Marc Müller, Thomas |
author_sort | Dong, Zhaowen |
collection | PubMed |
description | Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NMR spectroscopy and, in one case, the formal dimer, 2,4-disila-1λ(3),3λ(3)-digermetane, was isolated. The main products of these reactions are sila-bis-λ(3)-germiranes, i.e. directly interconnected digermylenes that are part of a three-membered ring. The structural data, supported by the results of density functional calculations confirm the digermylene nature of these products with a long inner cyclic Ge–Ge bond that decreases the inherent high ring strain in silagermiranes. |
format | Online Article Text |
id | pubmed-8115106 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-81151062021-06-02 Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene Dong, Zhaowen Winkler, Jan Mathis Schmidtmann, Marc Müller, Thomas Chem Sci Chemistry Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NMR spectroscopy and, in one case, the formal dimer, 2,4-disila-1λ(3),3λ(3)-digermetane, was isolated. The main products of these reactions are sila-bis-λ(3)-germiranes, i.e. directly interconnected digermylenes that are part of a three-membered ring. The structural data, supported by the results of density functional calculations confirm the digermylene nature of these products with a long inner cyclic Ge–Ge bond that decreases the inherent high ring strain in silagermiranes. The Royal Society of Chemistry 2021-03-22 /pmc/articles/PMC8115106/ /pubmed/34084426 http://dx.doi.org/10.1039/d1sc00956g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Dong, Zhaowen Winkler, Jan Mathis Schmidtmann, Marc Müller, Thomas Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title | Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title_full | Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title_fullStr | Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title_full_unstemmed | Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title_short | Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene |
title_sort | three-membered cyclic digermylenes stabilised by an n-heterocyclic carbene |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/ https://www.ncbi.nlm.nih.gov/pubmed/34084426 http://dx.doi.org/10.1039/d1sc00956g |
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