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Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene

Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NM...

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Detalles Bibliográficos
Autores principales: Dong, Zhaowen, Winkler, Jan Mathis, Schmidtmann, Marc, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/
https://www.ncbi.nlm.nih.gov/pubmed/34084426
http://dx.doi.org/10.1039/d1sc00956g