Cargando…
Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene
Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R(2)Si = Ge(Do) (R(2)Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NM...
Autores principales: | Dong, Zhaowen, Winkler, Jan Mathis, Schmidtmann, Marc, Müller, Thomas |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115106/ https://www.ncbi.nlm.nih.gov/pubmed/34084426 http://dx.doi.org/10.1039/d1sc00956g |
Ejemplares similares
-
SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes
por: Dong, Zhaowen, et al.
Publicado: (2020) -
Synthesis, Characterization, and Reaction of Digermylenes
por: Huo, Shuai‐Cong, et al.
Publicado: (2022) -
Actinide tetra-N-heterocyclic carbene ‘sandwiches’
por: DeJesus, Joseph F., et al.
Publicado: (2021) -
Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes
por: Samuel, Prinson P., et al.
Publicado: (2015) -
IPr# – highly hindered, broadly applicable N-heterocyclic carbenes
por: Zhao, Qun, et al.
Publicado: (2021)