Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)

We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe(4)][F(ClF)(3)] as well as the homologous polychloride [NPr(3)Me][Cl(7)]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl(2), respectively. Quantum-che...

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Detalles Bibliográficos
Autores principales: Pröhm, Patrick, Schwarze, Nico, Müller, Carsten, Steinhauer, Simon, Beckers, Helmut, Rupf, Susanne M., Riedel, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8117328/
https://www.ncbi.nlm.nih.gov/pubmed/33870378
http://dx.doi.org/10.1039/d1cc01088c
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author Pröhm, Patrick
Schwarze, Nico
Müller, Carsten
Steinhauer, Simon
Beckers, Helmut
Rupf, Susanne M.
Riedel, Sebastian
author_facet Pröhm, Patrick
Schwarze, Nico
Müller, Carsten
Steinhauer, Simon
Beckers, Helmut
Rupf, Susanne M.
Riedel, Sebastian
author_sort Pröhm, Patrick
collection PubMed
description We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe(4)][F(ClF)(3)] as well as the homologous polychloride [NPr(3)Me][Cl(7)]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl(2), respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)(3)](−) anion.
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spelling pubmed-81173282021-06-02 Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−) Pröhm, Patrick Schwarze, Nico Müller, Carsten Steinhauer, Simon Beckers, Helmut Rupf, Susanne M. Riedel, Sebastian Chem Commun (Camb) Chemistry We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe(4)][F(ClF)(3)] as well as the homologous polychloride [NPr(3)Me][Cl(7)]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl(2), respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)(3)](−) anion. The Royal Society of Chemistry 2021-04-07 /pmc/articles/PMC8117328/ /pubmed/33870378 http://dx.doi.org/10.1039/d1cc01088c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Pröhm, Patrick
Schwarze, Nico
Müller, Carsten
Steinhauer, Simon
Beckers, Helmut
Rupf, Susanne M.
Riedel, Sebastian
Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title_full Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title_fullStr Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title_full_unstemmed Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title_short Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
title_sort non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [f(clf)(3)](−)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8117328/
https://www.ncbi.nlm.nih.gov/pubmed/33870378
http://dx.doi.org/10.1039/d1cc01088c
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