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Route to tunable room temperature electric polarization in SrTiO(3)–CoFe(2)O(4) heterostructures

Utilizing the magnetostrictive properties of CoFe(2)O(4), we demonstrate reversible room temperature control of the Ti electronic structure in SrTiO(3)–CoFe(2)O(4) heterostructures, by inducing local and reversible strain in the SrTiO(3). By means of X-ray absorption spectroscopy, we have ascertaine...

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Detalles Bibliográficos
Autores principales: Maurel, Laura, Herrero-Martín, Javier, Motti, Federico, Vasili, Hari Babu, Piamonteze, Cinthia, Heyderman, Laura J., Scagnoli, Valerio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8118119/
https://www.ncbi.nlm.nih.gov/pubmed/34094567
http://dx.doi.org/10.1039/d0tc05821a
Descripción
Sumario:Utilizing the magnetostrictive properties of CoFe(2)O(4), we demonstrate reversible room temperature control of the Ti electronic structure in SrTiO(3)–CoFe(2)O(4) heterostructures, by inducing local and reversible strain in the SrTiO(3). By means of X-ray absorption spectroscopy, we have ascertained the changes that take place in the energy levels of the Ti 3d orbitals under the influence of an external magnetic field. The observed Ti electronic state when the sample is subjected to moderately large external magnetic fields and the disappearance of the induced phase upon their removal indicates lattice distortions that are suggestive of the development of a net electric polarization.