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Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122396/ https://www.ncbi.nlm.nih.gov/pubmed/33919013 http://dx.doi.org/10.3390/polym13091349 |
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author | Liu, Tianhao Wang, Ying Zhou, Jin Li, Mengyang Yue, Jinquan |
author_facet | Liu, Tianhao Wang, Ying Zhou, Jin Li, Mengyang Yue, Jinquan |
author_sort | Liu, Tianhao |
collection | PubMed |
description | In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated enzymatic hydrolysis lignin (HEHL) was prepared by hydroxylation modification of purified EHL with hydrogen peroxide (H(2)O(2)) and ferrous hydroxide (Fe(OH)(3)). HEHL was mixed uniformly with Lewis acid-modified fibers on a pressure machine and modified during the molding process. The purpose of Lewis acid degradation of hemicellulose-converted furfural with HEHL was to generate a resin structure to improve the mechanical properties of a MFPs. The microstructure of the MFP was shown to be generated by resin structure, and it was demonstrated that HEHL was compounded on Lewis acid-modified fibers during the molding process. The thermal stability of the MFP with composite HEHL did not change significantly owing to the addition of lignin and had higher tensile strength (46.28 MPa) and flexural strength (65.26 MPa) compared to uncompounded and modified MFP. The results of this study are expected to promote the application of high lignin content fibers in molded fibers. |
format | Online Article Text |
id | pubmed-8122396 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-81223962021-05-16 Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis Liu, Tianhao Wang, Ying Zhou, Jin Li, Mengyang Yue, Jinquan Polymers (Basel) Article In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated enzymatic hydrolysis lignin (HEHL) was prepared by hydroxylation modification of purified EHL with hydrogen peroxide (H(2)O(2)) and ferrous hydroxide (Fe(OH)(3)). HEHL was mixed uniformly with Lewis acid-modified fibers on a pressure machine and modified during the molding process. The purpose of Lewis acid degradation of hemicellulose-converted furfural with HEHL was to generate a resin structure to improve the mechanical properties of a MFPs. The microstructure of the MFP was shown to be generated by resin structure, and it was demonstrated that HEHL was compounded on Lewis acid-modified fibers during the molding process. The thermal stability of the MFP with composite HEHL did not change significantly owing to the addition of lignin and had higher tensile strength (46.28 MPa) and flexural strength (65.26 MPa) compared to uncompounded and modified MFP. The results of this study are expected to promote the application of high lignin content fibers in molded fibers. MDPI 2021-04-21 /pmc/articles/PMC8122396/ /pubmed/33919013 http://dx.doi.org/10.3390/polym13091349 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Liu, Tianhao Wang, Ying Zhou, Jin Li, Mengyang Yue, Jinquan Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title | Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title_full | Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title_fullStr | Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title_full_unstemmed | Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title_short | Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis |
title_sort | preparation of molded fiber products from hydroxylated lignin compounded with lewis acid-modified fibers its analysis |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122396/ https://www.ncbi.nlm.nih.gov/pubmed/33919013 http://dx.doi.org/10.3390/polym13091349 |
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