Cargando…

Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis

In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Tianhao, Wang, Ying, Zhou, Jin, Li, Mengyang, Yue, Jinquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122396/
https://www.ncbi.nlm.nih.gov/pubmed/33919013
http://dx.doi.org/10.3390/polym13091349
_version_ 1783692604722905088
author Liu, Tianhao
Wang, Ying
Zhou, Jin
Li, Mengyang
Yue, Jinquan
author_facet Liu, Tianhao
Wang, Ying
Zhou, Jin
Li, Mengyang
Yue, Jinquan
author_sort Liu, Tianhao
collection PubMed
description In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated enzymatic hydrolysis lignin (HEHL) was prepared by hydroxylation modification of purified EHL with hydrogen peroxide (H(2)O(2)) and ferrous hydroxide (Fe(OH)(3)). HEHL was mixed uniformly with Lewis acid-modified fibers on a pressure machine and modified during the molding process. The purpose of Lewis acid degradation of hemicellulose-converted furfural with HEHL was to generate a resin structure to improve the mechanical properties of a MFPs. The microstructure of the MFP was shown to be generated by resin structure, and it was demonstrated that HEHL was compounded on Lewis acid-modified fibers during the molding process. The thermal stability of the MFP with composite HEHL did not change significantly owing to the addition of lignin and had higher tensile strength (46.28 MPa) and flexural strength (65.26 MPa) compared to uncompounded and modified MFP. The results of this study are expected to promote the application of high lignin content fibers in molded fibers.
format Online
Article
Text
id pubmed-8122396
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-81223962021-05-16 Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis Liu, Tianhao Wang, Ying Zhou, Jin Li, Mengyang Yue, Jinquan Polymers (Basel) Article In this study, molded fiber products (MFPs) were prepared from lignin compounded with Lewis acid-modified fibers using enzymatic hydrolysis lignin (EHL) as a bio-phenol. The fibers were modified and compounded entirely through hot-pressing. To improve the reactivity of enzymatic lignin, hydroxylated enzymatic hydrolysis lignin (HEHL) was prepared by hydroxylation modification of purified EHL with hydrogen peroxide (H(2)O(2)) and ferrous hydroxide (Fe(OH)(3)). HEHL was mixed uniformly with Lewis acid-modified fibers on a pressure machine and modified during the molding process. The purpose of Lewis acid degradation of hemicellulose-converted furfural with HEHL was to generate a resin structure to improve the mechanical properties of a MFPs. The microstructure of the MFP was shown to be generated by resin structure, and it was demonstrated that HEHL was compounded on Lewis acid-modified fibers during the molding process. The thermal stability of the MFP with composite HEHL did not change significantly owing to the addition of lignin and had higher tensile strength (46.28 MPa) and flexural strength (65.26 MPa) compared to uncompounded and modified MFP. The results of this study are expected to promote the application of high lignin content fibers in molded fibers. MDPI 2021-04-21 /pmc/articles/PMC8122396/ /pubmed/33919013 http://dx.doi.org/10.3390/polym13091349 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liu, Tianhao
Wang, Ying
Zhou, Jin
Li, Mengyang
Yue, Jinquan
Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title_full Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title_fullStr Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title_full_unstemmed Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title_short Preparation of Molded Fiber Products from Hydroxylated Lignin Compounded with Lewis Acid-Modified Fibers Its Analysis
title_sort preparation of molded fiber products from hydroxylated lignin compounded with lewis acid-modified fibers its analysis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122396/
https://www.ncbi.nlm.nih.gov/pubmed/33919013
http://dx.doi.org/10.3390/polym13091349
work_keys_str_mv AT liutianhao preparationofmoldedfiberproductsfromhydroxylatedlignincompoundedwithlewisacidmodifiedfibersitsanalysis
AT wangying preparationofmoldedfiberproductsfromhydroxylatedlignincompoundedwithlewisacidmodifiedfibersitsanalysis
AT zhoujin preparationofmoldedfiberproductsfromhydroxylatedlignincompoundedwithlewisacidmodifiedfibersitsanalysis
AT limengyang preparationofmoldedfiberproductsfromhydroxylatedlignincompoundedwithlewisacidmodifiedfibersitsanalysis
AT yuejinquan preparationofmoldedfiberproductsfromhydroxylatedlignincompoundedwithlewisacidmodifiedfibersitsanalysis