Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid

The first coordination compound of copper and tiglic acid named tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II) was synthesized and crystallized from water solution. Its structure was determined and analyzed based on X-ray diffraction measurement. The paddle-wheel coordination system of the investig...

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Autores principales: Świątkowski, Marcin, Lanka, Suneel, Czylkowska, Agnieszka, Gas, Katarzyna, Sawicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122876/
https://www.ncbi.nlm.nih.gov/pubmed/33922582
http://dx.doi.org/10.3390/ma14092148
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author Świątkowski, Marcin
Lanka, Suneel
Czylkowska, Agnieszka
Gas, Katarzyna
Sawicki, Maciej
author_facet Świątkowski, Marcin
Lanka, Suneel
Czylkowska, Agnieszka
Gas, Katarzyna
Sawicki, Maciej
author_sort Świątkowski, Marcin
collection PubMed
description The first coordination compound of copper and tiglic acid named tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II) was synthesized and crystallized from water solution. Its structure was determined and analyzed based on X-ray diffraction measurement. The paddle-wheel coordination system of the investigated compound was compared with other similar copper structures known in the literature. The Hirshfeld analysis was used for the detailed analysis of intermolecular interaction. The new compound was also characterized in terms of infrared absorption, thermal, and magnetic properties. The antiferromagnetic coupling of copper ions was found.
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spelling pubmed-81228762021-05-16 Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid Świątkowski, Marcin Lanka, Suneel Czylkowska, Agnieszka Gas, Katarzyna Sawicki, Maciej Materials (Basel) Article The first coordination compound of copper and tiglic acid named tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II) was synthesized and crystallized from water solution. Its structure was determined and analyzed based on X-ray diffraction measurement. The paddle-wheel coordination system of the investigated compound was compared with other similar copper structures known in the literature. The Hirshfeld analysis was used for the detailed analysis of intermolecular interaction. The new compound was also characterized in terms of infrared absorption, thermal, and magnetic properties. The antiferromagnetic coupling of copper ions was found. MDPI 2021-04-23 /pmc/articles/PMC8122876/ /pubmed/33922582 http://dx.doi.org/10.3390/ma14092148 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Świątkowski, Marcin
Lanka, Suneel
Czylkowska, Agnieszka
Gas, Katarzyna
Sawicki, Maciej
Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title_full Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title_fullStr Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title_full_unstemmed Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title_short Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid
title_sort structural, spectroscopic, thermal, and magnetic properties of a new dinuclear copper coordination compound with tiglic acid
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122876/
https://www.ncbi.nlm.nih.gov/pubmed/33922582
http://dx.doi.org/10.3390/ma14092148
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