Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes

The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR(3))(2)], where (SiR(3) = SiMe(3) and SiMe(2)Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR(3))(Br)]. The structure of trans-[Pd(...

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Autores principales: Ansell, Melvyn B., Kostakis, George E., Navarro, Oscar, Spencer, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122886/
https://www.ncbi.nlm.nih.gov/pubmed/33922538
http://dx.doi.org/10.3390/molecules26092460
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author Ansell, Melvyn B.
Kostakis, George E.
Navarro, Oscar
Spencer, John
author_facet Ansell, Melvyn B.
Kostakis, George E.
Navarro, Oscar
Spencer, John
author_sort Ansell, Melvyn B.
collection PubMed
description The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR(3))(2)], where (SiR(3) = SiMe(3) and SiMe(2)Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR(3))(Br)]. The structure of trans-[Pd(ITMe)(2)(SiMe(2)Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.
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spelling pubmed-81228862021-05-16 Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes Ansell, Melvyn B. Kostakis, George E. Navarro, Oscar Spencer, John Molecules Communication The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR(3))(2)], where (SiR(3) = SiMe(3) and SiMe(2)Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR(3))(Br)]. The structure of trans-[Pd(ITMe)(2)(SiMe(2)Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration. MDPI 2021-04-23 /pmc/articles/PMC8122886/ /pubmed/33922538 http://dx.doi.org/10.3390/molecules26092460 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Ansell, Melvyn B.
Kostakis, George E.
Navarro, Oscar
Spencer, John
Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title_full Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title_fullStr Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title_full_unstemmed Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title_short Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes
title_sort synthesis of trans-mono(silyl)palladium(ii) bromide complexes
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122886/
https://www.ncbi.nlm.nih.gov/pubmed/33922538
http://dx.doi.org/10.3390/molecules26092460
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