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Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes

The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR(3))(2)], where (SiR(3) = SiMe(3) and SiMe(2)Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR(3))(Br)]. The structure of trans-[Pd(...

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Detalles Bibliográficos
Autores principales:	Ansell, Melvyn B., Kostakis, George E., Navarro, Oscar, Spencer, John
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Communication
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122886/ https://www.ncbi.nlm.nih.gov/pubmed/33922538 http://dx.doi.org/10.3390/molecules26092460

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