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Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer

Hydrophilic, flexible polyurethane (FPU) foams made from Hypol prepolymers are capable of retaining large amounts of water and saline solutions. The addition of different catalysts and surfactant agents to Hypol JM 5008 prepolymer was assayed to obtain a foam with good structural stability and elast...

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Autores principales: Borreguero, Ana M., Zamora, Javier, Garrido, Ignacio, Carmona, Manuel, Rodríguez, Juan F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8123336/
https://www.ncbi.nlm.nih.gov/pubmed/33922943
http://dx.doi.org/10.3390/ma14092197
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author Borreguero, Ana M.
Zamora, Javier
Garrido, Ignacio
Carmona, Manuel
Rodríguez, Juan F.
author_facet Borreguero, Ana M.
Zamora, Javier
Garrido, Ignacio
Carmona, Manuel
Rodríguez, Juan F.
author_sort Borreguero, Ana M.
collection PubMed
description Hydrophilic, flexible polyurethane (FPU) foams made from Hypol prepolymers are capable of retaining large amounts of water and saline solutions. The addition of different catalysts and surfactant agents to Hypol JM 5008 prepolymer was assayed to obtain a foam with good structural stability and elasticity. The combination of three catalysts, stannous octoate and two amine-based ones (Tegoamin 33 and Tegoamin BDE), and the surfactant Niax silicone L-620LV allowed to synthesize a foam with a homogeneous cell size distribution, exhibiting the highest saline absorption capacity (2.4 g/gram of foam) and almost complete shape recovery, with up to a 20% of remaining deformation. Then, superabsorbent sodium acrylate polymer (PNaA) was added to the FPU foam up to 8 pph. The urine absorption capacity of the foam was increased about 24.8% by incorporating 6 pph of PNaA, absorbing 17.46 g of saline solution per foam gram, without any negative impact on the rest of the foam properties. All these properties make the synthesized foams suitable for corporal fluids absorption applications in which elasticity and low-density are required.
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spelling pubmed-81233362021-05-16 Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer Borreguero, Ana M. Zamora, Javier Garrido, Ignacio Carmona, Manuel Rodríguez, Juan F. Materials (Basel) Article Hydrophilic, flexible polyurethane (FPU) foams made from Hypol prepolymers are capable of retaining large amounts of water and saline solutions. The addition of different catalysts and surfactant agents to Hypol JM 5008 prepolymer was assayed to obtain a foam with good structural stability and elasticity. The combination of three catalysts, stannous octoate and two amine-based ones (Tegoamin 33 and Tegoamin BDE), and the surfactant Niax silicone L-620LV allowed to synthesize a foam with a homogeneous cell size distribution, exhibiting the highest saline absorption capacity (2.4 g/gram of foam) and almost complete shape recovery, with up to a 20% of remaining deformation. Then, superabsorbent sodium acrylate polymer (PNaA) was added to the FPU foam up to 8 pph. The urine absorption capacity of the foam was increased about 24.8% by incorporating 6 pph of PNaA, absorbing 17.46 g of saline solution per foam gram, without any negative impact on the rest of the foam properties. All these properties make the synthesized foams suitable for corporal fluids absorption applications in which elasticity and low-density are required. MDPI 2021-04-25 /pmc/articles/PMC8123336/ /pubmed/33922943 http://dx.doi.org/10.3390/ma14092197 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Borreguero, Ana M.
Zamora, Javier
Garrido, Ignacio
Carmona, Manuel
Rodríguez, Juan F.
Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title_full Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title_fullStr Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title_full_unstemmed Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title_short Improving the Hydrophilicity of Flexible Polyurethane Foams with Sodium Acrylate Polymer
title_sort improving the hydrophilicity of flexible polyurethane foams with sodium acrylate polymer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8123336/
https://www.ncbi.nlm.nih.gov/pubmed/33922943
http://dx.doi.org/10.3390/ma14092197
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