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Hydrosilylation Reactions Catalyzed by Rhenium

Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alk...

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Autores principales: Wei, Duo, Buhaibeh, Ruqaya, Canac, Yves, Sortais, Jean-Baptiste
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8124788/
https://www.ncbi.nlm.nih.gov/pubmed/33946880
http://dx.doi.org/10.3390/molecules26092598
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author Wei, Duo
Buhaibeh, Ruqaya
Canac, Yves
Sortais, Jean-Baptiste
author_facet Wei, Duo
Buhaibeh, Ruqaya
Canac, Yves
Sortais, Jean-Baptiste
author_sort Wei, Duo
collection PubMed
description Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alkenes is summarized. Mechanisms of rhenium-catalyzed hydrosilylation are discussed.
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spelling pubmed-81247882021-05-17 Hydrosilylation Reactions Catalyzed by Rhenium Wei, Duo Buhaibeh, Ruqaya Canac, Yves Sortais, Jean-Baptiste Molecules Review Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alkenes is summarized. Mechanisms of rhenium-catalyzed hydrosilylation are discussed. MDPI 2021-04-29 /pmc/articles/PMC8124788/ /pubmed/33946880 http://dx.doi.org/10.3390/molecules26092598 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Wei, Duo
Buhaibeh, Ruqaya
Canac, Yves
Sortais, Jean-Baptiste
Hydrosilylation Reactions Catalyzed by Rhenium
title Hydrosilylation Reactions Catalyzed by Rhenium
title_full Hydrosilylation Reactions Catalyzed by Rhenium
title_fullStr Hydrosilylation Reactions Catalyzed by Rhenium
title_full_unstemmed Hydrosilylation Reactions Catalyzed by Rhenium
title_short Hydrosilylation Reactions Catalyzed by Rhenium
title_sort hydrosilylation reactions catalyzed by rhenium
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8124788/
https://www.ncbi.nlm.nih.gov/pubmed/33946880
http://dx.doi.org/10.3390/molecules26092598
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AT sortaisjeanbaptiste hydrosilylationreactionscatalyzedbyrhenium