“Broken-hearted” carbon bowl via electron shuttle reaction: energetics and electron coupling

Unprecedented one-step C[double bond, length as m-dash]C bond cleavage leading to opening of the buckybowl (π-bowl), that could provide access to carbon-rich structures with previously inaccessible topologies, is reported; highlighting the possibility to implement drastically different synthetic rou...

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Detalles Bibliográficos
Autores principales: Leith, Gabrielle A., Rice, Allison M., Yarbrough, Brandon J., Kittikhunnatham, Preecha, Mathur, Abhijai, Morris, Nicholas A., Francis, Megan J., Berseneva, Anna A., Dhull, Poonam, Adams, Richard D., Bobo, M. Victoria, Vannucci, Aaron A., Smith, Mark D., Garashchuk, Sophya, Shustova, Natalia B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8132954/
https://www.ncbi.nlm.nih.gov/pubmed/34040735
http://dx.doi.org/10.1039/d0sc06755e

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