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Controllable double CF(2)-insertion into sp(2) C–Cu bond using TMSCF(3): a facile access to tetrafluoroethylene-bridged structures

A highly efficient method for controllable double CF(2)-insertion into pentafluorophenylcopper species using TMSCF(3) as difluoromethylene source has been developed. The newly generated fluoroalkylcopper(i) species, C(6)F(5)CF(2)CF(2)Cu, shows good reactivity towards a myriad of structurally diverse...

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Detalles Bibliográficos
Autores principales:	Xie, Qiqiang, Zhu, Ziyue, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8133001/ https://www.ncbi.nlm.nih.gov/pubmed/34040722 http://dx.doi.org/10.1039/c9sc05018c

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