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Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances

The nanofiltration composite membranes were obtained by incorporation of KIT-6 ordered mesoporous silica, before and after its functionalization with amine groups, into polyphenylene-ether-ether-sulfone (PPEES) matrix. The incorporation of silica nanoparticles into PPEES polymer matrix was evidenced...

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Autores principales: Paun, Gabriela, Parvulescu, Viorica, Neagu, Elena, Albu, Camelia, Ionita, Larisa, Maxim, Monica Elisabeta, Munteanu, Andrei, Ciobanu, Madalina, Radu, Gabriel Lucian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8143004/
https://www.ncbi.nlm.nih.gov/pubmed/33918993
http://dx.doi.org/10.3390/membranes11050300
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author Paun, Gabriela
Parvulescu, Viorica
Neagu, Elena
Albu, Camelia
Ionita, Larisa
Maxim, Monica Elisabeta
Munteanu, Andrei
Ciobanu, Madalina
Radu, Gabriel Lucian
author_facet Paun, Gabriela
Parvulescu, Viorica
Neagu, Elena
Albu, Camelia
Ionita, Larisa
Maxim, Monica Elisabeta
Munteanu, Andrei
Ciobanu, Madalina
Radu, Gabriel Lucian
author_sort Paun, Gabriela
collection PubMed
description The nanofiltration composite membranes were obtained by incorporation of KIT-6 ordered mesoporous silica, before and after its functionalization with amine groups, into polyphenylene-ether-ether-sulfone (PPEES) matrix. The incorporation of silica nanoparticles into PPEES polymer matrix was evidenced by FTIR and UV–VIS spectroscopy. SEM images of the membranes cross-section and their surface topology, evidenced by AFM, showed a low effect of KIT-6 silica nanoparticles loading and functionalization. The performances of the obtained membranes were appraised in permeation of Chaenomeles japonica fruit extracts and the selective separation of phenolic acids and flavonoids. The obtained results proved that the PPEES with functionalized KIT-6 nanofiltration membrane, we have prepared, is suitable for the polyphenolic compound’s concentration from the natural extracts.
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spelling pubmed-81430042021-05-25 Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances Paun, Gabriela Parvulescu, Viorica Neagu, Elena Albu, Camelia Ionita, Larisa Maxim, Monica Elisabeta Munteanu, Andrei Ciobanu, Madalina Radu, Gabriel Lucian Membranes (Basel) Article The nanofiltration composite membranes were obtained by incorporation of KIT-6 ordered mesoporous silica, before and after its functionalization with amine groups, into polyphenylene-ether-ether-sulfone (PPEES) matrix. The incorporation of silica nanoparticles into PPEES polymer matrix was evidenced by FTIR and UV–VIS spectroscopy. SEM images of the membranes cross-section and their surface topology, evidenced by AFM, showed a low effect of KIT-6 silica nanoparticles loading and functionalization. The performances of the obtained membranes were appraised in permeation of Chaenomeles japonica fruit extracts and the selective separation of phenolic acids and flavonoids. The obtained results proved that the PPEES with functionalized KIT-6 nanofiltration membrane, we have prepared, is suitable for the polyphenolic compound’s concentration from the natural extracts. MDPI 2021-04-21 /pmc/articles/PMC8143004/ /pubmed/33918993 http://dx.doi.org/10.3390/membranes11050300 Text en © 2021 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Paun, Gabriela
Parvulescu, Viorica
Neagu, Elena
Albu, Camelia
Ionita, Larisa
Maxim, Monica Elisabeta
Munteanu, Andrei
Ciobanu, Madalina
Radu, Gabriel Lucian
Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title_full Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title_fullStr Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title_full_unstemmed Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title_short Nanofiltration Composite Membranes Based on KIT-6 and Functionalized KIT-6 Nanoparticles in a Polymeric Matrix with Enhanced Performances
title_sort nanofiltration composite membranes based on kit-6 and functionalized kit-6 nanoparticles in a polymeric matrix with enhanced performances
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8143004/
https://www.ncbi.nlm.nih.gov/pubmed/33918993
http://dx.doi.org/10.3390/membranes11050300
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